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Structure-Property Relationships in Novel Materials

Record Type:	Language materials, manuscript : Monograph/item
Title/Author:	Structure-Property Relationships in Novel Materials/
Author:	Seibel, Elizabeth M.
Description:	1 online resource (180 pages)
Notes:	Source: Dissertation Abstracts International, Volume: 78-11(E), Section: B.
Subject:	Organic chemistry. -
Online resource:	click for full text (PQDT)
ISBN:	9780355039481

Structure-Property Relationships in Novel Materials
Seibel, Elizabeth M.

Structure-Property Relationships in Novel Materials - 1 online resource (180 pages)

Source: Dissertation Abstracts International, Volume: 78-11(E), Section: B.

Thesis (Ph.D.)--Princeton University, 2017.

Includes bibliographical references

Part I. Frustrated Magnetism and Deintercalation of Honeycomb Oxides -- Part II. Electron-Precise Gold Intermetallics.

This thesis is a study of the structure-property relationships of novel materials, broken into two major parts. The first part, "Part I: Frustrated Magnetism and Deintercalation of Honeycomb Oxides" explores new, layered nickel oxides and their properties, specifically the synthesis, structure, magnetism, and applications of the Na3Ni 2BiO6-NaNi2BiO6-NaNi2BiO 6•1.7H2O system. These phases are of interest to the solid-state and physics communities because they display frustrated magnetism on a hexagonal lattice. Chapter 3 explores the chemistry and physics of Na 3Ni2BiO6; Chapter 4 then discusses its chemical deintercalation and subsequent hydration to form the NaNi2BiO 6-NaNi2BiO6•1.7H2O system. These phases are examples of sought-after spin-1/2 systems on a hexagonal lattice.

Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2018

Mode of access: World Wide Web

ISBN: 9780355039481Subjects--Topical Terms:

1148722
Organic chemistry.
Index Terms--Genre/Form:

554714
Electronic books.

Structure-Property Relationships in Novel Materials
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100 1 $a Seibel, Elizabeth M. $3 1187242
245 1 0 $a Structure-Property Relationships in Novel Materials
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300 $a 1 online resource (180 pages)
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500 $a Source: Dissertation Abstracts International, Volume: 78-11(E), Section: B.
500 $a Adviser: Robert J. Cava.
502 $a Thesis (Ph.D.)--Princeton University, 2017.
504 $a Includes bibliographical references
505 0 $a Part I. Frustrated Magnetism and Deintercalation of Honeycomb Oxides -- Part II. Electron-Precise Gold Intermetallics.
520 $a This thesis is a study of the structure-property relationships of novel materials, broken into two major parts. The first part, "Part I: Frustrated Magnetism and Deintercalation of Honeycomb Oxides" explores new, layered nickel oxides and their properties, specifically the synthesis, structure, magnetism, and applications of the Na3Ni 2BiO6-NaNi2BiO6-NaNi2BiO 6•1.7H2O system. These phases are of interest to the solid-state and physics communities because they display frustrated magnetism on a hexagonal lattice. Chapter 3 explores the chemistry and physics of Na 3Ni2BiO6; Chapter 4 then discusses its chemical deintercalation and subsequent hydration to form the NaNi2BiO 6-NaNi2BiO6•1.7H2O system. These phases are examples of sought-after spin-1/2 systems on a hexagonal lattice.
520 $a The second part of this thesis, "Part II: Electron-Precise Gold Intermetallics" explores novel, electron-precise intermetallics in the Lanthanide-gold-pnictide ternary system. The chemistry of gold-containing solids has not been well-studied despite gold's unusual physics, motivating the study. There are three new families discussed herein. The first, found in Chapter 7, is of the type LnAuSb (Ln = Lanthanide) which are new Dirac semimetals. The work illustrates a chemical design principle that can be used to predict new Dirac Semimetals, which is important given that the field of topological materials is rapidly growing. Chapter 8 discusses materials of the type LnAuBi2, which are layered intermetallics with a high degree of magnetic anisotropy. Finally, Chapter 9 explores new phases of the form Ln 3Au3Bi4. These materials are semiconductors with high Seebeck coefficients at room temperature, indicating their potential for use as thermoelectric materials.
533 $a Electronic reproduction. $b Ann Arbor, Mich. : $c ProQuest, $d 2018
538 $a Mode of access: World Wide Web
650 4 $a Organic chemistry. $3 1148722
650 4 $a Materials science. $3 557839
655 7 $a Electronic books. $2 local $3 554714
690 $a 0490
690 $a 0794
710 2 $a ProQuest Information and Learning Co. $3 1178819
710 2 $a Princeton University. $b Chemistry. $3 1182926
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10266327 $z click for full text (PQDT)