國立虎尾科技大學 |

Chemistry of Thioamides

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Chemistry of Thioamides/ edited by Toshiaki Murai.
其他作者:	Murai, Toshiaki.
面頁冊數:	VII, 238 p. 281 illus., 26 illus. in color.online resource. :
Contained By:	Springer Nature eBook
標題:	Organic chemistry. -
電子資源:	https://doi.org/10.1007/978-981-13-7828-7
ISBN:	9789811378287

Chemistry of Thioamides
Chemistry of Thioamides[electronic resource] /edited by Toshiaki Murai. - 1st ed. 2019. - VII, 238 p. 281 illus., 26 illus. in color.online resource.

1. Thioamides : Overview -- 2. Theoretical Aspects of Thioamides -- 3. Synthesis of Thioamides -- 4. Reaction of Thioamides -- 5. Asymmetric Synthesis Using Thioamides -- 6. Synthesis of Heterocycles from Thioamides -- 7.Thioamides-based Transition Metal-complexes -- 8. Thioamide-containing Peptides and Proteins.

This book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon–sulfur and carbon–carbon bonds, to asymmetric reactions, to formation of heterocycles are described. Among the array of thiocarbonyl compounds, thioamides are readily handled in room temperature air. Some of their characteristic features are that the polarity of C=S bonds in thioamides is much smaller than C=O bonds in ordinary amides, that thioamides possess higher HOMO and lower LUMO when compared with those of ordinary amides, and that carbon atoms alpha to the C=S and nitrogen atoms in thioamides are more acidic than those in ordinary amides. Theoretical studies further disclose their features. Thioamides are also used as ligands to a wide variety of metals. Their unique photophysical properties and catalytic activities are described here. Characteristic features of biologically relevant thioamides, e.g., thiopeptides and related compounds, are the final focus of the book. .

ISBN: 9789811378287

Standard No.: 10.1007/978-981-13-7828-7doiSubjects--Topical Terms:

1148722
Organic chemistry.

LC Class. No.: QD415-436

Dewey Class. No.: 547

Chemistry of Thioamides
LDR:02725nam a22003975i 4500 001 1012417
003 DE-He213
005 20200630134230.0
007 cr nn 008mamaa
008 210106s2019 si | s |||| 0|eng d
020 $a 9789811378287 $9 978-981-13-7828-7
024 7 $a 10.1007/978-981-13-7828-7 $2 doi
035 $a 978-981-13-7828-7
050 4 $a QD415-436
072 7 $a PNN $2 bicssc
072 7 $a SCI013040 $2 bisacsh
072 7 $a PNN $2 thema
082 0 4 $a 547 $2 23
245 1 0 $a Chemistry of Thioamides $h [electronic resource] / $c edited by Toshiaki Murai.
250 $a 1st ed. 2019.
264 1 $a Singapore : $b Springer Singapore : $b Imprint: Springer, $c 2019.
300 $a VII, 238 p. 281 illus., 26 illus. in color. $b online resource.
336 $a text $b txt $2 rdacontent
337 $a computer $b c $2 rdamedia
338 $a online resource $b cr $2 rdacarrier
347 $a text file $b PDF $2 rda
505 0 $a 1. Thioamides : Overview -- 2. Theoretical Aspects of Thioamides -- 3. Synthesis of Thioamides -- 4. Reaction of Thioamides -- 5. Asymmetric Synthesis Using Thioamides -- 6. Synthesis of Heterocycles from Thioamides -- 7.Thioamides-based Transition Metal-complexes -- 8. Thioamide-containing Peptides and Proteins.
520 $a This book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon–sulfur and carbon–carbon bonds, to asymmetric reactions, to formation of heterocycles are described. Among the array of thiocarbonyl compounds, thioamides are readily handled in room temperature air. Some of their characteristic features are that the polarity of C=S bonds in thioamides is much smaller than C=O bonds in ordinary amides, that thioamides possess higher HOMO and lower LUMO when compared with those of ordinary amides, and that carbon atoms alpha to the C=S and nitrogen atoms in thioamides are more acidic than those in ordinary amides. Theoretical studies further disclose their features. Thioamides are also used as ligands to a wide variety of metals. Their unique photophysical properties and catalytic activities are described here. Characteristic features of biologically relevant thioamides, e.g., thiopeptides and related compounds, are the final focus of the book. .
650 0 $a Organic chemistry. $3 1148722
650 0 $a Catalysis. $3 673438
650 1 4 $a Organic Chemistry. $3 673440
700 1 $a Murai, Toshiaki. $4 edt $4 http://id.loc.gov/vocabulary/relators/edt $3 1226813
710 2 $a SpringerLink (Online service) $3 593884
773 0 $t Springer Nature eBook
776 0 8 $i Printed edition: $z 9789811378270
776 0 8 $i Printed edition: $z 9789811378294
776 0 8 $i Printed edition: $z 9789811378300
856 4 0 $u https://doi.org/10.1007/978-981-13-7828-7
912 $a ZDB-2-CMS
912 $a ZDB-2-SXC
950 $a Chemistry and Materials Science (SpringerNature-11644)
950 $a Chemistry and Material Science (R0) (SpringerNature-43709)