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Chemistry of Thioamides

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Chemistry of Thioamides/ edited by Toshiaki Murai.
other author:	Murai, Toshiaki.
Description:	VII, 238 p. 281 illus., 26 illus. in color.online resource. :
Contained By:	Springer Nature eBook
Subject:	Organic chemistry. -
Online resource:	https://doi.org/10.1007/978-981-13-7828-7
ISBN:	9789811378287

Chemistry of Thioamides
Chemistry of Thioamides[electronic resource] /edited by Toshiaki Murai. - 1st ed. 2019. - VII, 238 p. 281 illus., 26 illus. in color.online resource.

1. Thioamides : Overview -- 2. Theoretical Aspects of Thioamides -- 3. Synthesis of Thioamides -- 4. Reaction of Thioamides -- 5. Asymmetric Synthesis Using Thioamides -- 6. Synthesis of Heterocycles from Thioamides -- 7.Thioamides-based Transition Metal-complexes -- 8. Thioamide-containing Peptides and Proteins.

This book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon–sulfur and carbon–carbon bonds, to asymmetric reactions, to formation of heterocycles are described. Among the array of thiocarbonyl compounds, thioamides are readily handled in room temperature air. Some of their characteristic features are that the polarity of C=S bonds in thioamides is much smaller than C=O bonds in ordinary amides, that thioamides possess higher HOMO and lower LUMO when compared with those of ordinary amides, and that carbon atoms alpha to the C=S and nitrogen atoms in thioamides are more acidic than those in ordinary amides. Theoretical studies further disclose their features. Thioamides are also used as ligands to a wide variety of metals. Their unique photophysical properties and catalytic activities are described here. Characteristic features of biologically relevant thioamides, e.g., thiopeptides and related compounds, are the final focus of the book. .

ISBN: 9789811378287

Standard No.: 10.1007/978-981-13-7828-7doiSubjects--Topical Terms:

1148722
Organic chemistry.

LC Class. No.: QD415-436

Dewey Class. No.: 547

Chemistry of Thioamides
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520 $a This book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon–sulfur and carbon–carbon bonds, to asymmetric reactions, to formation of heterocycles are described. Among the array of thiocarbonyl compounds, thioamides are readily handled in room temperature air. Some of their characteristic features are that the polarity of C=S bonds in thioamides is much smaller than C=O bonds in ordinary amides, that thioamides possess higher HOMO and lower LUMO when compared with those of ordinary amides, and that carbon atoms alpha to the C=S and nitrogen atoms in thioamides are more acidic than those in ordinary amides. Theoretical studies further disclose their features. Thioamides are also used as ligands to a wide variety of metals. Their unique photophysical properties and catalytic activities are described here. Characteristic features of biologically relevant thioamides, e.g., thiopeptides and related compounds, are the final focus of the book. .
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