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Metallo-Supramolecular Polymers = Synthesis, Properties, and Device Applications /

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Metallo-Supramolecular Polymers/ by Masayoshi Higuchi.
Reminder of title:	Synthesis, Properties, and Device Applications /
Author:	Higuchi, Masayoshi.
Description:	IX, 89 p. 41 illus., 1 illus. in color.online resource. :
Contained By:	Springer Nature eBook
Subject:	Polymers . -
Online resource:	https://doi.org/10.1007/978-4-431-56891-9
ISBN:	9784431568919

Metallo-Supramolecular Polymers = Synthesis, Properties, and Device Applications /
Higuchi, Masayoshi.

Metallo-Supramolecular PolymersSynthesis, Properties, and Device Applications /[electronic resource] :by Masayoshi Higuchi. - 1st ed. 2019. - IX, 89 p. 41 illus., 1 illus. in color.online resource. - NIMS Monographs,2197-8891. - NIMS Monographs,.

Introduction -- Fe(II)-based metallo-supramolecular polymers -- Ru(II)-based metallo-supramolecular polymers -- Co(II)-based metallo-supramolecular polymers -- Zn(II)-based metallo-supramolecular polymers -- Cu(II)-based metallo-supramolecular polymers -- Pt(II)-based metallo-supramolecular polymers -- Ni(II)-based metallo-supramolecular polymers -- Mo(VI)-based metallo-supramolecular polymer -- Cd(II)-based metallo-supramolecular polymer -- Eu(III)-based metallo-supramolecular polymer -- Summary.

This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.

ISBN: 9784431568919

Standard No.: 10.1007/978-4-431-56891-9doiSubjects--Topical Terms:

1253577
Polymers .

LC Class. No.: QD380-388

Dewey Class. No.: 541.2254

Metallo-Supramolecular Polymers = Synthesis, Properties, and Device Applications /
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505 0 $a Introduction -- Fe(II)-based metallo-supramolecular polymers -- Ru(II)-based metallo-supramolecular polymers -- Co(II)-based metallo-supramolecular polymers -- Zn(II)-based metallo-supramolecular polymers -- Cu(II)-based metallo-supramolecular polymers -- Pt(II)-based metallo-supramolecular polymers -- Ni(II)-based metallo-supramolecular polymers -- Mo(VI)-based metallo-supramolecular polymer -- Cd(II)-based metallo-supramolecular polymer -- Eu(III)-based metallo-supramolecular polymer -- Summary.
520 $a This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.
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