國立虎尾科技大學 |

Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles/ by Hyung Yoon.
作者:	Yoon, Hyung.
面頁冊數:	XXIX, 212 p. 552 illus., 35 illus. in color.online resource. :
Contained By:	Springer Nature eBook
標題:	Physical Chemistry. -
電子資源:	https://doi.org/10.1007/978-3-030-54077-7
ISBN:	9783030540777

Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles
Yoon, Hyung.

Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles[electronic resource] /by Hyung Yoon. - 1st ed. 2020. - XXIX, 212 p. 552 illus., 35 illus. in color.online resource. - Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053. - Springer Theses, Recognizing Outstanding Ph.D. Research,.

Chapter 1. Carbohalogenation Catalyzed by Palladium and Nickel -- Chapter 2. Diastereoselective Pd-Catalyzed Aryl Cyanation and Aryl Borylation -- Chapter 3. Pd-Catalyzed Spirocyclization via C–H Activation and Benzyne/Alkyne Insertion.

This book presents Pd- and Ni-catalyzed transformations generating functionalized heterocycles. Transition metal catalysis is at the forefront of synthetic organic chemistry since it offers new and powerful methods to forge carbon–carbon bonds in high atom- and step-economy. In Chapter 1, the author describes a Pd- and Ni-catalyzed cycloisomerization of aryl iodides to alkyl iodides, known as carboiodination. In the context of the Pd-catalyzed variant, the chapter explores the production of enantioenriched carboxamides through diastereoselective Pd-catalyzed carboiodination. It then discusses Ni-catalyzed reactions to generate oxindoles and an enantioselective variant employing a dual ligand system. Chapter 2 introduces readers to a Pd-catalyzed diastereoselective anion-capture cascade. It also examines diastereoselective Pd-catalyzed aryl cyanation to synthesize alkyl nitriles, a method that generates high yields of borylated chromans as a single diastereomer, and highlights its synthetic utility. Lastly, Chapter 3 presents a Pd-catalyzed domino process harnessing carbopalladation, C–H activation and π-system insertion (benzynes and alkynes) to generate spirocycles. It also describes the mechanistic studies performed on these reactions.

ISBN: 9783030540777

Standard No.: 10.1007/978-3-030-54077-7doiSubjects--Topical Terms:

668972
Physical Chemistry.

LC Class. No.: QD505

Dewey Class. No.: 541.395

Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles
LDR:02980nam a22004095i 4500 001 1021379
003 DE-He213
005 20200902083314.0
007 cr nn 008mamaa
008 210318s2020 gw | s |||| 0|eng d
020 $a 9783030540777 $9 978-3-030-54077-7
024 7 $a 10.1007/978-3-030-54077-7 $2 doi
035 $a 978-3-030-54077-7
050 4 $a QD505
072 7 $a PNRD $2 bicssc
072 7 $a SCI013060 $2 bisacsh
072 7 $a PNRD $2 thema
082 0 4 $a 541.395 $2 23
100 1 $a Yoon, Hyung. $e author. $4 aut $4 http://id.loc.gov/vocabulary/relators/aut $3 1317031
245 1 0 $a Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles $h [electronic resource] / $c by Hyung Yoon.
250 $a 1st ed. 2020.
264 1 $a Cham : $b Springer International Publishing : $b Imprint: Springer, $c 2020.
300 $a XXIX, 212 p. 552 illus., 35 illus. in color. $b online resource.
336 $a text $b txt $2 rdacontent
337 $a computer $b c $2 rdamedia
338 $a online resource $b cr $2 rdacarrier
347 $a text file $b PDF $2 rda
490 1 $a Springer Theses, Recognizing Outstanding Ph.D. Research, $x 2190-5053
505 0 $a Chapter 1. Carbohalogenation Catalyzed by Palladium and Nickel -- Chapter 2. Diastereoselective Pd-Catalyzed Aryl Cyanation and Aryl Borylation -- Chapter 3. Pd-Catalyzed Spirocyclization via C–H Activation and Benzyne/Alkyne Insertion.
520 $a This book presents Pd- and Ni-catalyzed transformations generating functionalized heterocycles. Transition metal catalysis is at the forefront of synthetic organic chemistry since it offers new and powerful methods to forge carbon–carbon bonds in high atom- and step-economy. In Chapter 1, the author describes a Pd- and Ni-catalyzed cycloisomerization of aryl iodides to alkyl iodides, known as carboiodination. In the context of the Pd-catalyzed variant, the chapter explores the production of enantioenriched carboxamides through diastereoselective Pd-catalyzed carboiodination. It then discusses Ni-catalyzed reactions to generate oxindoles and an enantioselective variant employing a dual ligand system. Chapter 2 introduces readers to a Pd-catalyzed diastereoselective anion-capture cascade. It also examines diastereoselective Pd-catalyzed aryl cyanation to synthesize alkyl nitriles, a method that generates high yields of borylated chromans as a single diastereomer, and highlights its synthetic utility. Lastly, Chapter 3 presents a Pd-catalyzed domino process harnessing carbopalladation, C–H activation and π-system insertion (benzynes and alkynes) to generate spirocycles. It also describes the mechanistic studies performed on these reactions.
650 2 4 $a Physical Chemistry. $3 668972
650 2 4 $a Organometallic Chemistry. $3 674440
650 2 4 $a Organic Chemistry. $3 673440
650 2 4 $a Inorganic Chemistry. $3 671307
650 0 $a Physical chemistry. $3 1148725
650 0 $a Organometallic chemistry . $3 1254952
650 0 $a Organic chemistry. $3 1148722
650 0 $a Inorganic chemistry. $3 1182077
650 0 $a Catalysis. $3 673438
710 2 $a SpringerLink (Online service) $3 593884
773 0 $t Springer Nature eBook
776 0 8 $i Printed edition: $z 9783030540760
776 0 8 $i Printed edition: $z 9783030540784
776 0 8 $i Printed edition: $z 9783030540791
830 0 $a Springer Theses, Recognizing Outstanding Ph.D. Research, $x 2190-5053 $3 1253569
856 4 0 $u https://doi.org/10.1007/978-3-030-54077-7
912 $a ZDB-2-CMS
912 $a ZDB-2-SXC
950 $a Chemistry and Materials Science (SpringerNature-11644)
950 $a Chemistry and Material Science (R0) (SpringerNature-43709)