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Synthesis of Optically Active Oxymethylenehelicene Oligomers and Self-assembly Phenomena at a Liquid–Solid Interface

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Synthesis of Optically Active Oxymethylenehelicene Oligomers and Self-assembly Phenomena at a Liquid–Solid Interface/ by Tsukasa Sawato.
作者:	Sawato, Tsukasa.
面頁冊數:	XII, 83 p. 67 illus., 59 illus. in color.online resource. :
Contained By:	Springer Nature eBook
標題:	Organic Chemistry. -
電子資源:	https://doi.org/10.1007/978-981-15-3192-7
ISBN:	9789811531927

Synthesis of Optically Active Oxymethylenehelicene Oligomers and Self-assembly Phenomena at a Liquid–Solid Interface
Sawato, Tsukasa.

Synthesis of Optically Active Oxymethylenehelicene Oligomers and Self-assembly Phenomena at a Liquid–Solid Interface[electronic resource] /by Tsukasa Sawato. - 1st ed. 2020. - XII, 83 p. 67 illus., 59 illus. in color.online resource. - Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053. - Springer Theses, Recognizing Outstanding Ph.D. Research,.

1. Introduction -- 2. Fibril Film Formation of Pseudoenantiomeric Oxymethylenehelicene Oligomers at the Liquid-Solid Interface -- 3. Mechanical Stirring Induces Heteroaggregate Formation and Self-assembly of Pseudoenantiomeric Oxymethylenehelicene Oligomers in Solution -- 4. Proximate Stochastic Chiral Symmetry Breaking by Racemic Oxymethylenehelicene Oligomers -- 5. Conclusions -- 6. Experimental Section.

In this book, the author demonstrates that double-helix formation and fibril film formation occur on solid surfaces as a result of the catalytic effect of the liquid–solid interface of the newly synthesized helicene oligomer. In addition, he shows that the double helix produced at the liquid–solid interface can be diffused into a solution to form a self-assembling material by means of mechanical stirring. Both types of formation are new chemical phenomena unique to liquid–solid interfaces not found in solutions. Detailed results are provided for new chemical reactions at liquid–solid interfaces, and gleaned from experiments performed using synthetic organic molecules. The book offers a useful reference guide to elucidating reaction mechanisms for researchers whose work involves chemical phenomena at a liquid–solid interface. .

ISBN: 9789811531927

Standard No.: 10.1007/978-981-15-3192-7doiSubjects--Topical Terms:

673440
Organic Chemistry.

LC Class. No.: QD450-882

Dewey Class. No.: 541

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