國立虎尾科技大學 |

Studies on Green Synthetic Reactions Based on Formic Acid from Biomass

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Studies on Green Synthetic Reactions Based on Formic Acid from Biomass/ by Ming-Chen Fu.
作者:	Fu, Ming-Chen.
面頁冊數:	XIV, 105 p. 189 illus., 24 illus. in color.online resource. :
Contained By:	Springer Nature eBook
標題:	Organic Chemistry. -
電子資源:	https://doi.org/10.1007/978-981-15-7623-2
ISBN:	9789811576232

Studies on Green Synthetic Reactions Based on Formic Acid from Biomass
Fu, Ming-Chen.

Studies on Green Synthetic Reactions Based on Formic Acid from Biomass[electronic resource] /by Ming-Chen Fu. - 1st ed. 2020. - XIV, 105 p. 189 illus., 24 illus. in color.online resource. - Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053. - Springer Theses, Recognizing Outstanding Ph.D. Research,.

Introduction -- Conversion of Formic Acid as C1 building block on Organic Synthesis -- Non-Metal Boron-Catalyzed N-methylation Conversion of Amines with Formic Acid -- Nickel-Catalyzed Hydrocarboxylation of Alkynes with Formic Acid through Catalytic CO Recycling -- Efficient Pd-Catalyzed Carboxylation of Allylic Alcohols with Formic Acid -- Conclusions.

This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized α, β- and β, γ-unsaturated carboxylic acids. The findings presented not only enrich the field of ‘C1 chemistry,’ but also support the advancement of green and sustainable chemistry. .

ISBN: 9789811576232

Standard No.: 10.1007/978-981-15-7623-2doiSubjects--Topical Terms:

673440
Organic Chemistry.

LC Class. No.: QD505

Dewey Class. No.: 541.395

Studies on Green Synthetic Reactions Based on Formic Acid from Biomass
LDR:02634nam a22004095i 4500 001 1021780
003 DE-He213
005 20200810184724.0
007 cr nn 008mamaa
008 210318s2020 si | s |||| 0|eng d
020 $a 9789811576232 $9 978-981-15-7623-2
024 7 $a 10.1007/978-981-15-7623-2 $2 doi
035 $a 978-981-15-7623-2
050 4 $a QD505
072 7 $a PNRD $2 bicssc
072 7 $a SCI013060 $2 bisacsh
072 7 $a PNRD $2 thema
082 0 4 $a 541.395 $2 23
100 1 $a Fu, Ming-Chen. $e author. $4 aut $4 http://id.loc.gov/vocabulary/relators/aut $3 1317463
245 1 0 $a Studies on Green Synthetic Reactions Based on Formic Acid from Biomass $h [electronic resource] / $c by Ming-Chen Fu.
250 $a 1st ed. 2020.
264 1 $a Singapore : $b Springer Singapore : $b Imprint: Springer, $c 2020.
300 $a XIV, 105 p. 189 illus., 24 illus. in color. $b online resource.
336 $a text $b txt $2 rdacontent
337 $a computer $b c $2 rdamedia
338 $a online resource $b cr $2 rdacarrier
347 $a text file $b PDF $2 rda
490 1 $a Springer Theses, Recognizing Outstanding Ph.D. Research, $x 2190-5053
505 0 $a Introduction -- Conversion of Formic Acid as C1 building block on Organic Synthesis -- Non-Metal Boron-Catalyzed N-methylation Conversion of Amines with Formic Acid -- Nickel-Catalyzed Hydrocarboxylation of Alkynes with Formic Acid through Catalytic CO Recycling -- Efficient Pd-Catalyzed Carboxylation of Allylic Alcohols with Formic Acid -- Conclusions.
520 $a This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized α, β- and β, γ-unsaturated carboxylic acids. The findings presented not only enrich the field of ‘C1 chemistry,’ but also support the advancement of green and sustainable chemistry. .
650 2 4 $a Organic Chemistry. $3 673440
650 2 4 $a Green Chemistry. $3 1142255
650 0 $a Organic chemistry. $3 1148722
650 0 $a Green chemistry. $3 981746
650 0 $a Catalysis. $3 673438
710 2 $a SpringerLink (Online service) $3 593884
773 0 $t Springer Nature eBook
776 0 8 $i Printed edition: $z 9789811576225
776 0 8 $i Printed edition: $z 9789811576249
776 0 8 $i Printed edition: $z 9789811576256
830 0 $a Springer Theses, Recognizing Outstanding Ph.D. Research, $x 2190-5053 $3 1253569
856 4 0 $u https://doi.org/10.1007/978-981-15-7623-2
912 $a ZDB-2-CMS
912 $a ZDB-2-SXC
950 $a Chemistry and Materials Science (SpringerNature-11644)
950 $a Chemistry and Material Science (R0) (SpringerNature-43709)