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Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties/ by Mingoo Jin.
作者:	Jin, Mingoo.
面頁冊數:	X, 191 p. 169 illus., 149 illus. in color.online resource. :
Contained By:	Springer Nature eBook
標題:	Inorganic Chemistry. -
電子資源:	https://doi.org/10.1007/978-981-15-4063-9
ISBN:	9789811540639

Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties
Jin, Mingoo.

Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties[electronic resource] /by Mingoo Jin. - 1st ed. 2020. - X, 191 p. 169 illus., 149 illus. in color.online resource. - Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053. - Springer Theses, Recognizing Outstanding Ph.D. Research,.

1. General Introduction -- 2. Introduction of a Biphenyl Moiety for a Solvent Responsive Aryl Gold(I) -- 3. Luminescent Mechanochromism of a Chiral Complex: Distinct Crystal Structures and Color Changes of Racemic and Homochiral Gold(I) Isocyanide Complexes with a Binaphthyl Moiety -- 4. Mechano-Responsive Luminescence via Crystal-to-Crystal Phase Transitions between Chiral and Non-Chiral Space Groups -- 5. Mechanical-Stimulation-Triggered and Solvent-Vapor-Induced Reverse Single-Crystal-to-Single-Crystal Phase Transitions with Alterations of the Luminescence Color -- 6. Thermo-Responsive Phosphorescence Control Mediated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of Phosphane-Gold(I) Complex -- 7. Conclusion.

This book highlights and investigates novel solid-state luminescent properties of crystals with stimuli-responsive behavior. Several novel molecular designs for controlling crystal structures with photo-physical properties are described, with a special focus on external stimuli-responsive properties. The major goal of the material design concept was to capitalize on the chirality of crystals with stimuli-responsive properties. To allow crystals’ chirality to be controlled and modified by means of external stimulation, the axial chirality of biaryl moiety was employed and, interestingly, produced several novel mechano- and vapo-responsive luminescent properties based on crystal-to-crystal or single-crystal-to-single-crystal phase transitions. In addition, the book details how the molecular rotation of luminophores in the solid phase can be used to achieve corresponding thermal-responsive phosphorescence. The reports presented here illustrate how the author has succeeded in controlling structural factors in a bulk environment by using molecular design with linking to photo-physical properties. The content will be of great interest to researchers in the field, and to members of chemical and material science societies. .

ISBN: 9789811540639

Standard No.: 10.1007/978-981-15-4063-9doiSubjects--Topical Terms:

671307
Inorganic Chemistry.

LC Class. No.: QD410-412.5

Dewey Class. No.: 547.05

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