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Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields/ by Youngwook Park.
Author:	Park, Youngwook.
Description:	XVI, 41 p. 7 illus., 6 illus. in color.online resource. :
Contained By:	Springer Nature eBook
Subject:	Atomic structure . -
Online resource:	https://doi.org/10.1007/978-981-15-8693-4
ISBN:	9789811586934

Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields
Park, Youngwook.

Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields[electronic resource] /by Youngwook Park. - 1st ed. 2020. - XVI, 41 p. 7 illus., 6 illus. in color.online resource. - Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053. - Springer Theses, Recognizing Outstanding Ph.D. Research,.

Introduction -- Method.-. Electric Field-Control of Inversion Dynamics of Ammonia in an Argon Matrix -- Spectroscopic Evidence of Large Protonic Polarizability of Hydrogen Chloride–Water Complexes -- Summary.

This book describes the manipulation of molecular properties, such as orientation, structure, and dynamics, of small molecules and molecular clusters isolated in cold inert matrices by using unprecedentedly strong external electrostatic fields. Manipulation of molecules with controllable external forces is a dream of chemists. Molecules are inherently quantum-mechanical systems, control of which potentially can lead to quantum technology, such as quantum sensing and computing. This book demonstrates a combination of the ice film nanocapacitor method and the matrix isolation technique enabled the application of intense external dc electric fields across the isolated molecules and molecular clusters. Changes in molecular states induced by fields were monitored by means of vibrational spectroscopy. Also, the book presents manipulations of the inversion tunneling dynamics of ammonia molecule and the dislocation of acidic proton in hydrogen chloride–water complex. The book shows that the vibrational spectroscopy with the aid of unprecedentedly strong dc electric field can provide rich information on the electrostatic behaviors of molecules and molecular clusters, which underlie the understanding of intermolecular processes and molecular manipulation.

ISBN: 9789811586934

Standard No.: 10.1007/978-981-15-8693-4doiSubjects--Topical Terms:

1253596
Atomic structure .

LC Class. No.: QC173.4.A87

Dewey Class. No.: 539

Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields
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