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Oxide-Ion Conduction in the Dion–Jacobson-Type Layered Perovskites

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Oxide-Ion Conduction in the Dion–Jacobson-Type Layered Perovskites/ by Wenrui Zhang.
作者:	Zhang, Wenrui.
面頁冊數:	XII, 123 p. 94 illus., 89 illus. in color.online resource. :
Contained By:	Springer Nature eBook
標題:	Materials for Energy and Catalysis. -
電子資源:	https://doi.org/10.1007/978-981-19-2247-3
ISBN:	9789811922473

Oxide-Ion Conduction in the Dion–Jacobson-Type Layered Perovskites
Zhang, Wenrui.

Oxide-Ion Conduction in the Dion–Jacobson-Type Layered Perovskites[electronic resource] /by Wenrui Zhang. - 1st ed. 2022. - XII, 123 p. 94 illus., 89 illus. in color.online resource. - Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5061. - Springer Theses, Recognizing Outstanding Ph.D. Research,.

1. Introduction -- 2. New Oxide-ion conductors of Dion–Jacobson-Type Layered Perovskites CsBi2Ti2NbO10-δ and CsBi2–xMxTi2+yNb1–yO10‐x/2–y/2–δ (M = Mg, Ca, Sr and Ba; x = 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6; y = 0.2, 0.1, –0.1, and –0.2) -- 3. New Oxide-ion conductors of Dion–Jacobson- Type Layered Perovskites CsLn2Ti2NbO10 (Ln = La, Pr, Nd, Sm, Gd, Ho and Yb) and CsLa2–xMxTi2+yNb1–yO10–x/2–y/2 (M = Ca, Sr and Ba; x = 0, 0.1; y = 0.1, 0 and –0.1) -- 4. Conclusion and Future Work. .

This book reports a study of a class of Dion–Jacobson-type layered perovskite oxides in which high oxide-ion conductivities in phases were discovered for the first time in the world. The oxide-ion conductors are important in various energy conversion devices and environmental protection applications such as solid-oxide fuel cells, oxygen gas sensors, oxygen separation membranes, and oxygen-based catalysts. The discoveries are based on a new screening method, called the bond valence method, combined with an original design concept. The present finding of high oxide-ion conductivity reported in the thesis suggested the potential of Dion–Jacobson phases as a platform to identify superior oxide-ion conductors. To understand what causes such high oxide-ion conductivities in these layered perovskite oxides, the author analyzed their crystal structures at high temperature and described the relationship between oxide-ion conductivities and their crystal structures. A deep understanding of the mechanisms of oxide-ion diffusivity at an atomic level in the Dion–Jacobson phases is clarified. The discovery of these materials, the new screening method, and the original design concept make possible the realization of many environment-friendly technologies. The findings in this thesis facilitate the possibilities for many novel applications that will help lead to a sustainable future. .

ISBN: 9789811922473

Standard No.: 10.1007/978-981-19-2247-3doiSubjects--Topical Terms:

1366011
Materials for Energy and Catalysis.

LC Class. No.: TA401-492

Dewey Class. No.: 620.198

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