國立虎尾科技大學 |

Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes = Simple Synthetic Methods for Multinuclear Complexes Using Various C-C Coupling Reactions /

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes / by Yasuomi Yamazaki.
其他題名:	Simple Synthetic Methods for Multinuclear Complexes Using Various C-C Coupling Reactions /
作者:	Yamazaki, Yasuomi.
面頁冊數:	XIII, 105 p. 98 illus., 73 illus. in color.online resource. :
Contained By:	Springer Nature eBook
標題:	Physical Chemistry. -
電子資源:	https://doi.org/10.1007/978-981-16-7148-7
ISBN:	9789811671487

Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes = Simple Synthetic Methods for Multinuclear Complexes Using Various C-C Coupling Reactions /
Yamazaki, Yasuomi.

Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes Simple Synthetic Methods for Multinuclear Complexes Using Various C-C Coupling Reactions /[electronic resource] :by Yasuomi Yamazaki. - 1st ed. 2022. - XIII, 105 p. 98 illus., 73 illus. in color.online resource. - Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5061. - Springer Theses, Recognizing Outstanding Ph.D. Research,.

General Introduction -- Synthesis of Multinuclear Complexes Using the Mizoroki-Heck reaction -- Selective Synthesis of Various Photofunctional Multinuclear Complexes Using Combination of the Mizoroki-Heck Reaction and the Homo-coupling Reaction -- Photochemical and Electrochemical Hydrogenation of Pi Conjugated Bridging Ligands on Photofunctional Multinuclear Complexes -- Synthesis of Novel Multinuclear Complexes for Light-harvesting Systems Using the Coupling Reactions with Ring-shaped Multinuclear Re(I) Complexes as Building Blocks -- Conclusions. .

This book presents several helpful synthetic methods for diverse multinuclear complexes. The results described can be used to selectively connect mononuclear as well as multinuclear complexes with other metal complexes to construct valuable photofunctional compounds. Using the new synthetic methods, it was possible to selectively connect several types of metal complexes in a single step under relatively mild reaction conditions. This so-called building block approach utilizes various C–C coupling reactions between metal complexes with functional groups as active moieties. Owing to the large pi-conjugation systems, the multinuclear complexes synthesized using coupling reactions showed a strong absorption ability over a wide range of visible light and long emission lifetimes, which are ideal properties for photosensitizers and light absorbers. By combining these coupling methods with the newly developed hydrogenation reactions, the binding mode of the linkers in multinuclear complexes can be modified in order to tune the photophysical properties and photocatalytic ability. As such, the synthesized multinuclear complexes can be used for various purposes, e.g., as photocatalysts and photosensitizers, and in light-harvesting systems. The synthetic methods and strategies presented in this book diversify not only the structures but also functions of multinuclear complexes.

ISBN: 9789811671487

Standard No.: 10.1007/978-981-16-7148-7doiSubjects--Topical Terms:

668972
Physical Chemistry.

LC Class. No.: QD410-412.5

Dewey Class. No.: 547.05

Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes = Simple Synthetic Methods for Multinuclear Complexes Using Various C-C Coupling Reactions /
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