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Optoelectronic Properties of Metal Chalcogenide Nanoparticles : = Inter-band Transition Resonance and Chiroptical Effect.

紀錄類型:	書目-語言資料,手稿 : Monograph/item
正題名/作者:	Optoelectronic Properties of Metal Chalcogenide Nanoparticles :/
其他題名:	Inter-band Transition Resonance and Chiroptical Effect.
作者:	Yao, Yuan.
面頁冊數:	1 online resource (312 pages)
附註:	Source: Dissertations Abstracts International, Volume: 85-12, Section: B.
Contained By:	Dissertations Abstracts International85-12B.
標題:	Optometry. -
電子資源:	click for full text (PQDT)
ISBN:	9798382840642

Optoelectronic Properties of Metal Chalcogenide Nanoparticles : = Inter-band Transition Resonance and Chiroptical Effect.
Yao, Yuan.

Optoelectronic Properties of Metal Chalcogenide Nanoparticles :Inter-band Transition Resonance and Chiroptical Effect. - 1 online resource (312 pages)

Source: Dissertations Abstracts International, Volume: 85-12, Section: B.

Thesis (Ph.D.)--Cornell University, 2024.

Includes bibliographical references

The emergence of nanomaterials, driven by the size-dependent quantum confinement effect, has opened new possibilities for researchers to manipulate material properties by simply adjusting particle sizes. It continues to captivate us that by controlling the size and morphology of nanoparticles, a vast range of novel material properties and applications can be achieved. Among various classes of nanomaterials, optoelectronic nanomaterials have gained significant attention due to their immense potential in industries such as semiconductors. This thesis focuses on investigating two types of innovative semiconductor nanomaterials with distinct optoelectronic properties. The first material of interest is CuFeS2 nanoparticle, which belongs to the category of intermediate-band semiconductor nanomaterials. The second material is CdS magic size cluster hierarchical thin film, representing an intriguing inorganic/organic hybrid hierarchical chiral material. By utilizing these two materials as model systems, the primary objective of this thesis is to establish fundamental knowledge that will facilitate future advancements in similar materials. Each study is accompanied by a summary of the background, motivation, and summary, as outlined below.Part 1: CuFeS2 (chalcopyrite) exhibits a yellowish color and metallic luster in its natural bulk form, often leading to confusion with gold. However, CuFeS2 nanoparticles display entirely different optical properties. Upon dispersion in a solvent, they exhibit a deep red/purple color, characterized by a visible absorption band centered around 500 nm. The optical absorption characteristics of CuFeS2 nanoparticles have garnered significant research attention, as they resemble those of precious metal plasmonic nanoparticles like gold and silver. Furthermore, as CuFeS2 is a semiconductor, its absorption properties can be adjusted through post-synthetic modifications of chemical composition and crystal structure. However, previous literature presents conflicting accounts regarding the existence of the 500 nm absorption band, the underlying mechanism behind it, and the oxidation states of the cations involved. In this study, we establish our synthesis method for CuFeS2 nanoparticles and address these unresolved questions through a combination of advanced ex-situ and in-situ material characterization techniques. These include x-ray absorption spectroscopy (XAS) and x-ray emission spectroscopy (XES), along with material properties simulations such as density functional theory (DFT) and linear optical Lorentzian modeling.Part 2: Historically, chiral materials have garnered significant attention in the pharmaceutical industry due to the human body's stereoselective chemical reactions, where drugs with opposite chirality can have distinct effects. Apart from their stereoselective chemical properties, optically active chiral materials exhibit differential absorption of left-handed and right-handed light, which is characterized by circular dichroism (CD). However, it's important to note that achiral materials with linear anisotropic contributions, such as linear dichroism (LD) and linear birefringence (LB), can also result in a CD signal. This linear anisotropy-induced CD signal becomes more pronounced in complex material systems, particularly in hierarchically structured nanomaterials that encompass a wide range of length scales, from molecular-scale nanoclusters to micron-sized assemblies. Our recent research has demonstrated the self-assembly of CdS magic-sized clusters (MSCs) into ordered films with a hierarchical structure spanning seven orders of length scales. These films exhibit a strong circular dichroism (CD) response, but the chiral origins are obscured by the hierarchical architecture and contributions from linear anisotropy (linear dichroism, linear birefringence). Using first principle analysis, we have derived and validated a four-scan averaging method for extracting the "pure" CD signal, which specifically arises from structural dissymmetry, from hierarchical MSCs films. Using four-scan averaging method, we successfully characterized the true CD signal of our films, and identified the chiral assembly of our film as the chiral origin. To test the limit of the four-scan averaging method, we simulated the higher order linear anisotropy pairwise interaction and found the threshold at which our four scan method is no longer applicable. Additionally, to study MSCs with difference chemical composition, we conducted a mechanistic study on CdS MSC cation exchange reaction and found an interesting two steps reaction mechanism.

Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2024

Mode of access: World Wide Web

ISBN: 9798382840642Subjects--Topical Terms:

789248
Optometry.
Subjects--Index Terms:

ChiralityIndex Terms--Genre/Form:

554714
Electronic books.

Optoelectronic Properties of Metal Chalcogenide Nanoparticles : = Inter-band Transition Resonance and Chiroptical Effect.
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