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Production of Neo Acids From Biomass-Derived Monomers.

紀錄類型:	書目-語言資料,手稿 : Monograph/item
正題名/作者:	Production of Neo Acids From Biomass-Derived Monomers./
作者:	Andini, Erha Gelania.
面頁冊數:	1 online resource (53 pages)
附註:	Source: Masters Abstracts International, Volume: 85-09.
Contained By:	Masters Abstracts International85-09.
標題:	Energy. -
電子資源:	click for full text (PQDT)
ISBN:	9798381852097

Production of Neo Acids From Biomass-Derived Monomers.
Andini, Erha Gelania.

Production of Neo Acids From Biomass-Derived Monomers. - 1 online resource (53 pages)

Source: Masters Abstracts International, Volume: 85-09.

Thesis (M.Ch.E.)--University of Delaware, 2024.

Includes bibliographical references

Neo acids are highly branched carboxylic acids currently produced from fossil fuels. In this work, we produce renewable neo acids from lignocellulosic biomass-derived furan and keto acids via C-C coupling through hydroxyalkylation/alkylation (HAA), followed by ring-opening of furans through hydrodeoxygenation (HDO). We show effective C-C coupling over acid catalysts. Catalyst screening and multi-parameter optimization using machine learning optimize the yield and elucidate the correlation between variables and outcomes. We demonstrate selective furan ring-opening without affecting the carboxylic acid to make neo acids using a co-catalyst involving Pd supported on carbon and metal triflate.

Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2024

Mode of access: World Wide Web

ISBN: 9798381852097Subjects--Topical Terms:

784773
Energy.
Subjects--Index Terms:

Branched carboxylic acidsIndex Terms--Genre/Form:

554714
Electronic books.

Production of Neo Acids From Biomass-Derived Monomers.
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520 $a Neo acids are highly branched carboxylic acids currently produced from fossil fuels. In this work, we produce renewable neo acids from lignocellulosic biomass-derived furan and keto acids via C-C coupling through hydroxyalkylation/alkylation (HAA), followed by ring-opening of furans through hydrodeoxygenation (HDO). We show effective C-C coupling over acid catalysts. Catalyst screening and multi-parameter optimization using machine learning optimize the yield and elucidate the correlation between variables and outcomes. We demonstrate selective furan ring-opening without affecting the carboxylic acid to make neo acids using a co-catalyst involving Pd supported on carbon and metal triflate.
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538 $a Mode of access: World Wide Web
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650 4 $a Engineering. $3 561152
650 4 $a Chemical engineering. $3 555952
653 $a Branched carboxylic acids
653 $a Furans
653 $a Hydrodeoxygenation
653 $a Hydroxyalkylation/alkylation
653 $a Renewable neo acids
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