國立虎尾科技大學 |

Electronic structures and bonding interaction of structurally defined gold/silver superatoms = probed by anion photoelectron spectroscopy /

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Electronic structures and bonding interaction of structurally defined gold/silver superatoms/ by Shun Ito.
其他題名:	probed by anion photoelectron spectroscopy /
作者:	Ito, Shun.
出版者:	Singapore :Springer Nature Singapore : : 2025.,
面頁冊數:	xiii, 112 p. :ill., digital ; : 24 cm.;
附註:	"Doctoral thesis accepted by the University of Tokyo, Tokyo, Japan."
Contained By:	Springer Nature eBook
標題:	Nanoparticles. -
電子資源:	https://doi.org/10.1007/978-981-96-2892-6
ISBN:	9789819628926

Electronic structures and bonding interaction of structurally defined gold/silver superatoms = probed by anion photoelectron spectroscopy /
Ito, Shun.

Electronic structures and bonding interaction of structurally defined gold/silver superatomsprobed by anion photoelectron spectroscopy /[electronic resource] :by Shun Ito. - Singapore :Springer Nature Singapore :2025. - xiii, 112 p. :ill., digital ;24 cm. - Springer theses, recognizing outstanding Ph.D. research,2190-5061. - Springer theses, recognizing outstanding Ph.D. research..

"Doctoral thesis accepted by the University of Tokyo, Tokyo, Japan."

Chapter 1.Introduction -- Chapter 2.Experimental Setup of Anion Photoelectron Spectroscopy -- Chapter 3.Effect of Heterometal Doping on Electron Affinities of Eight Electron Superatoms -- Chapter 4.Effect of Ligand Substitution on Electron Affinities of Eight Electron Superatoms -- Chapter 5.Bonding Interaction in Homonuclear Superatomic Molecules -- Chapter 6.Bonding Interaction in Heteronuclear Superatomic Molecules -- Chapter 7.Summary and prospects.

This book focuses on ligand-protected gold clusters featuring their atomically precise compositions and unambiguous structures. They mimic electronic shell structures of atoms and are called structurally defined superatoms. The book describes the design principle of superatomic electronic structures and the bonding theory of superatoms as revealed by gas-phase anion photoelectron spectroscopy, which is conducted by using a state-of-the-art home-built apparatus and sheds light on fundamental electronic structures such as density of states and electron affinities otherwise elusive. This study revealed that the energy level of superatomic orbitals can be tuned coarsely by the heterometal doping and finely by the stepwise ligand exchange, respectively. The bonding theory of superatoms was also developed by anion photoelectron spectroscopy of homonuclear and heteronuclear superatoms. The comprehensive review of superatoms and detailed explanation of the apparatus were described in addition to individual studies. This book provides design principles of structurally defined superatoms and stimulates future research on the chemical and physical properties of superatoms.

ISBN: 9789819628926

Standard No.: 10.1007/978-981-96-2892-6doiSubjects--Topical Terms:

596762
Nanoparticles.

LC Class. No.: QC454.P48

Dewey Class. No.: 543.62

Electronic structures and bonding interaction of structurally defined gold/silver superatoms = probed by anion photoelectron spectroscopy /
LDR:02924nam a2200373 a 4500 001 1160567
003 DE-He213
005 20250314115245.0
006 m d
007 cr nn 008maaau
008 251029s2025 si s 0 eng d
020 $a 9789819628926 $q (electronic bk.)
020 $a 9789819628919 $q (paper)
024 7 $a 10.1007/978-981-96-2892-6 $2 doi
035 $a 978-981-96-2892-6
040 $a GP $c GP
041 0 $a eng
050 4 $a QC454.P48
072 7 $a TBN $2 bicssc
072 7 $a TGM $2 bicssc
072 7 $a SCI013050 $2 bisacsh
072 7 $a TBN $2 thema
072 7 $a PDT $2 thema
082 0 4 $a 543.62 $2 23
090 $a QC454.P48 $b I89 2025
100 1 $a Ito, Shun. $3 1487643
245 1 0 $a Electronic structures and bonding interaction of structurally defined gold/silver superatoms $h [electronic resource] : $b probed by anion photoelectron spectroscopy / $c by Shun Ito.
260 $a Singapore : $c 2025. $b Springer Nature Singapore : $b Imprint: Springer,
300 $a xiii, 112 p. : $b ill., digital ; $c 24 cm.
490 1 $a Springer theses, recognizing outstanding Ph.D. research, $x 2190-5061
500 $a "Doctoral thesis accepted by the University of Tokyo, Tokyo, Japan."
505 0 $a Chapter 1.Introduction -- Chapter 2.Experimental Setup of Anion Photoelectron Spectroscopy -- Chapter 3.Effect of Heterometal Doping on Electron Affinities of Eight Electron Superatoms -- Chapter 4.Effect of Ligand Substitution on Electron Affinities of Eight Electron Superatoms -- Chapter 5.Bonding Interaction in Homonuclear Superatomic Molecules -- Chapter 6.Bonding Interaction in Heteronuclear Superatomic Molecules -- Chapter 7.Summary and prospects.
520 $a This book focuses on ligand-protected gold clusters featuring their atomically precise compositions and unambiguous structures. They mimic electronic shell structures of atoms and are called structurally defined superatoms. The book describes the design principle of superatomic electronic structures and the bonding theory of superatoms as revealed by gas-phase anion photoelectron spectroscopy, which is conducted by using a state-of-the-art home-built apparatus and sheds light on fundamental electronic structures such as density of states and electron affinities otherwise elusive. This study revealed that the energy level of superatomic orbitals can be tuned coarsely by the heterometal doping and finely by the stepwise ligand exchange, respectively. The bonding theory of superatoms was also developed by anion photoelectron spectroscopy of homonuclear and heteronuclear superatoms. The comprehensive review of superatoms and detailed explanation of the apparatus were described in addition to individual studies. This book provides design principles of structurally defined superatoms and stimulates future research on the chemical and physical properties of superatoms.
650 2 4 $a Nanoparticles. $3 596762
650 2 4 $a Density Functional Theory. $3 1391717
650 2 4 $a Spectroscopy. $3 1102161
650 1 4 $a Nanochemistry. $3 596891
650 0 $a Silver. $3 1066274
650 0 $a Gold. $3 761231
650 0 $a Nanostructured materials. $3 557162
650 0 $a lectronic structure. $3 1487644
650 0 $a Photoelectron spectroscopy. $3 905440
710 2 $a SpringerLink (Online service) $3 593884
773 0 $t Springer Nature eBook
830 0 $a Springer theses, recognizing outstanding Ph.D. research. $3 883089
856 4 0 $u https://doi.org/10.1007/978-981-96-2892-6
950 $a Chemistry and Materials Science (SpringerNature-11644)