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Emerging analytical techniques for chemical speciation studies.. Part 1,. Electrochemical and migration methods

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Emerging analytical techniques for chemical speciation studies./ Michel Meyer, Demetrio Milea.
remainder title:	Electrochemical and migration methods
other author:	Demetrio, Milea.
Published:	Singapore :World Scientific, : c2025.,
Description:	1 online resource (292 p.)
Subject:	Speciation (Chemistry) -
Online resource:	https://www.worldscientific.com/worldscibooks/10.1142/13537#t=toc
ISBN:	9789811281099

Emerging analytical techniques for chemical speciation studies.. Part 1,. Electrochemical and migration methods
Emerging analytical techniques for chemical speciation studies.Part 1,Electrochemical and migration methods[electronic resource] /Electrochemical and migration methodsMichel Meyer, Demetrio Milea. - 1st ed. - Singapore :World Scientific,c2025. - 1 online resource (292 p.) - Series on chemistry, energy and the environment ;vol. 15. - Series on chemistry, energy and the environment ;v. 1.

Includes bibliographical references and index.

Intro -- Contents -- Preface -- 1 A Unified Approach in the Voltammetric and Potentiometric Studies of Metal-Ligand Equilibria: Theory and Practical Guide -- I. List of Abbreviations -- II. Introduction -- III. Nomenclature Used and Applicable Mathematical Models -- A. Nomenclature -- B. Mathematical Expressions Applicable to Speciation by Voltammetry -- C. Mathematical Expressions Applicable to Speciation by Potentiometry -- IV. Impact of Kinetics on the Shape and Placement of Recorded Curves -- A. Fully Labile M-L-OH Systems -- B. Inert and Non-labile Metal Complex(es) -- C. Mixed M-L Systems Containing Labile and Non-labile/Inert Complexes -- D. An Example of Fast Heterogeneous but Sluggish Homogeneous Kinetics -- V. Experimental Complex Formation Curves (ECFCs) -- A. Plot of Corrected Shifts (CSpH(i)) vs. pH in Predicting Major MpLqHr or MpLqOHr Species Formed -- B. Plot of Corrected Shifts (CSpH(i)) vs. log [L] in Predicting Major MpLq Species Formed -- VI. Protocol to Compute Excellent Estimates for Formation Constants -- VII. Computed Complex Formation Curve (CCFC) and Its Use in Modelling of a M-L-OH System and Refinement of Formation Constants -- A. Examples of CCFCs Used in Preliminary Modelling -- B. CCFCs Used in Final Modelling -- VIII. Virtual Potential and Voltammetry as a Virtual Potentiometric Sensor -- IX. Species Distribution Diagrams in Designing Experiments and Verifying the Proposed M-L-OH Model -- A. Species Distribution Diagrams as a Function of pH -- B. Predicting Shifts in Potential, ΔE -- C. Species Distribution Diagrams as a Function of the Total Ligand Concentration -- D. Confirming Additional Species -- E. General Guidelines -- X. Practical Guide to Executing Experiments -- A. General Considerations for Experiments -- B. Glass Electrode Calibration -- C. Polarographic Experiments -- 1. pH titrations.

ISBN: 9789811281099Subjects--Topical Terms:

1059652
Speciation (Chemistry)

LC Class. No.: QD75.3 / .E447 2025

Dewey Class. No.: 543

Emerging analytical techniques for chemical speciation studies.. Part 1,. Electrochemical and migration methods
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300 $a 1 online resource (292 p.)
490 1 $a Series on chemistry, energy and the environment ; $v vol. 15
504 $a Includes bibliographical references and index.
505 0 $a Intro -- Contents -- Preface -- 1 A Unified Approach in the Voltammetric and Potentiometric Studies of Metal-Ligand Equilibria: Theory and Practical Guide -- I. List of Abbreviations -- II. Introduction -- III. Nomenclature Used and Applicable Mathematical Models -- A. Nomenclature -- B. Mathematical Expressions Applicable to Speciation by Voltammetry -- C. Mathematical Expressions Applicable to Speciation by Potentiometry -- IV. Impact of Kinetics on the Shape and Placement of Recorded Curves -- A. Fully Labile M-L-OH Systems -- B. Inert and Non-labile Metal Complex(es) -- C. Mixed M-L Systems Containing Labile and Non-labile/Inert Complexes -- D. An Example of Fast Heterogeneous but Sluggish Homogeneous Kinetics -- V. Experimental Complex Formation Curves (ECFCs) -- A. Plot of Corrected Shifts (CSpH(i)) vs. pH in Predicting Major MpLqHr or MpLqOHr Species Formed -- B. Plot of Corrected Shifts (CSpH(i)) vs. log [L] in Predicting Major MpLq Species Formed -- VI. Protocol to Compute Excellent Estimates for Formation Constants -- VII. Computed Complex Formation Curve (CCFC) and Its Use in Modelling of a M-L-OH System and Refinement of Formation Constants -- A. Examples of CCFCs Used in Preliminary Modelling -- B. CCFCs Used in Final Modelling -- VIII. Virtual Potential and Voltammetry as a Virtual Potentiometric Sensor -- IX. Species Distribution Diagrams in Designing Experiments and Verifying the Proposed M-L-OH Model -- A. Species Distribution Diagrams as a Function of pH -- B. Predicting Shifts in Potential, ΔE -- C. Species Distribution Diagrams as a Function of the Total Ligand Concentration -- D. Confirming Additional Species -- E. General Guidelines -- X. Practical Guide to Executing Experiments -- A. General Considerations for Experiments -- B. Glass Electrode Calibration -- C. Polarographic Experiments -- 1. pH titrations.
505 8 $a 2. Ligand titrations -- D. Experiments Under Very Acidic Conditions -- E. Ion Selective Electrode Calibration -- XI. Recommended Instrumentation, Automation and Data Collection for Potentiometry and Voltammetry -- XII. A Practical Guide in Evaluation of Polarographic Signals -- A. Polarographic Signals -- B. Analysis of DP Polarograms -- C. Analysis of DC Polarograms -- D. Extraction of Reversible Half-wave Potentials from Non-reversible DCP Wave -- E. Treatment of Overlapping Polarographic Signals -- XIII. General Conclusions -- XIV. References -- 2 AGNES, an Equilibrium Technique for the Robust Speciation of Metals and Metalloids -- I. List of Abbreviations -- II. List of Symbols -- A. Latin Symbols -- B. Greek Symbols -- III. Introduction -- IV. Fundamentals of AGNES Technique -- A. Principles of AGN -- 1. First stage: reaching equilibrium with a known gain -- 2. Second stage: quantifying the accumulation -- B. Variants for the First Stage. Trajectory -- 1. One pulse: AGNES-1P -- 2. Two pulses: AGNES-2P -- C. Variants for the Second Stage -- 1. AGNES-I -- 2. AGNES-Q -- 3. AGNELSV -- 4. AGNES-SCP -- D. Working Electrodes -- 1. Mercury electrodes -- 2. Non-mercury electrodes -- E. Deposition Times -- 1. Rules of time in solutions with just the free analyte -- 2. The impact of complexes. Helping factor -- 3. Irreversible systems -- V. Validation of AGNES in Simple Sol -- VI. Application of AGNES in Humic Acid Dispersions -- VII. Application of AGNES in Natural Samples -- VIII. Application of AGNES in Dispersions of Nanomaterials -- A. Zn-based Nanomaterials -- B. Other Metal Ions -- IX. Application of AGNES for [In3+] and [Sb(OH)3] Determination -- A. Trivalent Redox States -- B. Indium -- C. Antimony -- X. Conclusions -- XI. Acknowledgments -- XII. References -- 3 Metal-Ligand Speciation Using Electromigration Techniques -- I. List of Abbreviations.
505 8 $a II. Principles of Electromigration -- III. Methods -- A. Capillary Zone Electrophoresis -- B. Isotachophoresis -- C. Capillary Isoelectric Focusing -- IV. Prerequisites -- V. Charge -- VI. Degree of Oxidation -- VII. Structure -- A. Determination of Intramolecular Metal-Ligand Distances by External Calibration -- B. Determination of the Coordination Modes of Labile Metal-Ligand Complexes -- VIII. Speciation -- A. Case of Stable Complexes -- 1. Capillary electrophoresis -- 2. Isotachophoresis -- B. Case of Labile Complexes -- 1. Capillary zone electrophoresis -- 2. Isotachophoresis -- IX. Topological Speciation -- X. Special Cases -- A. Protonated Complexes -- B. Invisible Complexes -- XI. General Conclusions -- XII. References -- 4 Thermo-Optical Measurement Methods to Study Biomolecular Interactions - Microscale Thermophoresis and More -- I. List of Abbreviations -- II. List of Symbols -- III. Introduction -- A. Capillary Based Measurements -- B. Multiwell Plate Based Temperature Related Intensity Change Measurements -- IV. Experimental Guidelines -- A. Conducting an MST/TRIC Experiment -- B. Choosing the Dye and Optimizing Labeling -- C. EC50 and Kd -- V. Typical Applications -- A. Screening for Small Molecule Binding -- B. Competitive Binding Assays -- C. Emerging Fields -- 1. PROTACs -- 2. Gene therapy -- 3. Neurodegenerative diseases -- 4. Membrane proteins -- 5. Plant science -- 6. Vaccines -- VI. Beyond Affinity Measurements -- A. Stoichiometry -- B. Van't Hoff Analysis -- C. Concentration Determination of Ligand With a Calibration Curve -- D. Measuring Enzyme Kinetics -- E. Parallel Kd Measurement and Determination of Ligand Concentration -- VII. Practical Tips for Complex Data -- A. Ligand Induced Fluorescence Change (LIFC) -- B. Real Versus Apparent Biphasic Behavior -- VIII. Conclusion -- IX. References -- Index.
588 $a Description based on publisher supplied metadata and other sources.
650 0 $a Speciation (Chemistry) $3 1059652
700 1 $a Demetrio, Milea. $3 1497645
700 1 $a Michel, Meyer. $3 1497646
830 0 $a Series on chemistry, energy and the environment ; $v v. 1 $3 1236600
856 4 0 $u https://www.worldscientific.com/worldscibooks/10.1142/13537#t=toc