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Polar organometallic reagents = synthesis, structure, properties and applications /
紀錄類型:
書目-語言資料,印刷品 : Monograph/item
正題名/作者:
Polar organometallic reagents/ edited by Andrew E. H. Wheatley, Masanobu Uchiyama.
其他題名:
synthesis, structure, properties and applications /
其他作者:
Wheatley, Andrew.
出版者:
Hoboken, NJ :John Wiley & Sons, : 2022.,
面頁冊數:
1 online resource :ill. (some col.) :
標題:
Organometallic chemistry. -
電子資源:
https://onlinelibrary.wiley.com/doi/book/10.1002/9781119448877
ISBN:
9781119448877
Polar organometallic reagents = synthesis, structure, properties and applications /
Polar organometallic reagents
synthesis, structure, properties and applications /[electronic resource] :edited by Andrew E. H. Wheatley, Masanobu Uchiyama. - 1st ed. - Hoboken, NJ :John Wiley & Sons,2022. - 1 online resource :ill. (some col.)
Includes bibliographical references and index.
"Polar organometallic compounds are important reagents in synthetic chemistry; these compounds are highly reactive due to the large polarization of their metal-carbon bond. Traditional examples such as organolithium and Grignard reagents have been studied and used for fundamental organic transformations since the early 20th Century, but the study of polar organometallics has undergone a revolution in the last decade. In solution the advent of new techniques has allowed the detailed investigation of reaction mechanisms and, in particular, the elucidation of active species in ways not previously achievable. The other major development is the advent of so-called synergic reagents. This new field that combines two organometallic reagents to give reagents that combine excellent basicity with poor nucleophilicity has opened up myriad organic transformations that would hitherto have been impossible using straightforward chemistry"--
ISBN: 9781119448877Subjects--Topical Terms:
674453
Organometallic chemistry.
LC Class. No.: QD411 / .P63 2022
Dewey Class. No.: 547/.05
Polar organometallic reagents = synthesis, structure, properties and applications /
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"Polar organometallic compounds are important reagents in synthetic chemistry; these compounds are highly reactive due to the large polarization of their metal-carbon bond. Traditional examples such as organolithium and Grignard reagents have been studied and used for fundamental organic transformations since the early 20th Century, but the study of polar organometallics has undergone a revolution in the last decade. In solution the advent of new techniques has allowed the detailed investigation of reaction mechanisms and, in particular, the elucidation of active species in ways not previously achievable. The other major development is the advent of so-called synergic reagents. This new field that combines two organometallic reagents to give reagents that combine excellent basicity with poor nucleophilicity has opened up myriad organic transformations that would hitherto have been impossible using straightforward chemistry"--
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https://onlinelibrary.wiley.com/doi/book/10.1002/9781119448877
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