國立虎尾科技大學 |

Dye sensitized solar cells based on nanowire sculptured thin film titanium dioxide photoanodes.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Dye sensitized solar cells based on nanowire sculptured thin film titanium dioxide photoanodes./
Author:	Pursel, Sean M.
Description:	163 p.
Notes:	Source: Dissertation Abstracts International, Volume: 73-06, Section: B, page: .
Contained By:	Dissertation Abstracts International73-06B.
Subject:	Alternative Energy. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3501023
ISBN:	9781267217288

Dye sensitized solar cells based on nanowire sculptured thin film titanium dioxide photoanodes.
Pursel, Sean M.

Dye sensitized solar cells based on nanowire sculptured thin film titanium dioxide photoanodes. - 163 p.

Source: Dissertation Abstracts International, Volume: 73-06, Section: B, page: .

Thesis (Ph.D.)--The Pennsylvania State University, 2011.

Energy harvested from the sun using photovoltaics (PVs) is a renewable resource in high demand. Photovoltaics convert photons into electron-hole pairs which are then separated and used for electrical power. 75 TW of energy arrives from the sun every year onto US soil. Harvesting it all would provide enough energy to power the entire world for more than five years. It is this abundance of energy that makes PVs an attractive alternative to fossil fuels. PVs currently produce 0.15% of the energy consumed in the US. Production needs to grow as the worldwide demand for energy is projected to almost double by 2050.

ISBN: 9781267217288Subjects--Topical Terms:

845381
Alternative Energy.

Dye sensitized solar cells based on nanowire sculptured thin film titanium dioxide photoanodes.
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020 $a 9781267217288
035 $a (UMI)AAI3501023
035 $a AAI3501023
040 $a UMI $c UMI
100 1 $a Pursel, Sean M. $3 845555
245 1 0 $a Dye sensitized solar cells based on nanowire sculptured thin film titanium dioxide photoanodes.
300 $a 163 p.
500 $a Source: Dissertation Abstracts International, Volume: 73-06, Section: B, page: .
500 $a Adviser: Mark W. Horn.
502 $a Thesis (Ph.D.)--The Pennsylvania State University, 2011.
520 $a Energy harvested from the sun using photovoltaics (PVs) is a renewable resource in high demand. Photovoltaics convert photons into electron-hole pairs which are then separated and used for electrical power. 75 TW of energy arrives from the sun every year onto US soil. Harvesting it all would provide enough energy to power the entire world for more than five years. It is this abundance of energy that makes PVs an attractive alternative to fossil fuels. PVs currently produce 0.15% of the energy consumed in the US. Production needs to grow as the worldwide demand for energy is projected to almost double by 2050.
520 $a Fundamental and device based PV research have made steady efficiency gains in silicon based devices and thin film devices have started to become commercially viable. However, less expensive devices with suitable efficiency have not been fully developed. Dye sensitized solar cells (DSSCs) are one such device which has been optimized using standard components. However, device efficiency has not increased significantly since DSSCs were first conceived in 1991. Interestingly, none of the standard components are optimized, but act in a synergistic way in the most efficient devices. This research, along with other parallel research, attempts to optimize a single component of DSSCs with the goal of combining efforts to produce a device with increased efficiency.
520 $a This research attempts to optimize the TiO2 photoanode used in DSSCs in terms of electron collection, dye coverage, light harvesting, and novel electrolyte infiltration by replacing the standard colloidal structure with nanowires deposited using physical vapor deposition at an oblique angle to form sculptured thin films. The results are quantified through standard photovoltaic testing, electrochemical impedance spectroscopy, UV-Vis-NIR spectroscopy, and general materials characterization techniques. The nanowire photoanodes are engineered during deposition using reactive evaporation, substrate heating, substrate positioning/movement, and co-deposition. The influence of substrate roughness, source material, and post deposition processing in device performance is also quantified.
520 $a The novel nanowire sculptured thin film photoanodes are shown to have the ability to advantageously modulate dye coverage, electron lifetime, light scattering, and pore spacing more than the standard colloidal photoanode. Device performance using standard dye and electrolyte is shown to be closely matched to that of colloidal based devices constructed as control samples. Along with optimized dye and electrolytes these nanowire based photoanodes should be considered for the research and development of a fully optimized DSSC which would operate more efficiently than the current state of the art.
590 $a School code: 0176.
650 4 $a Alternative Energy. $3 845381
650 4 $a Nanotechnology. $3 557660
650 4 $a Engineering, Materials Science. $3 845422
690 $a 0363
690 $a 0652
690 $a 0794
710 2 $a The Pennsylvania State University. $3 845556
773 0 $t Dissertation Abstracts International $g 73-06B.
790 1 0 $a Horn, Mark W., $e advisor
790 $a 0176
791 $a Ph.D.
792 $a 2011
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3501023