國立虎尾科技大學 |

Bonding in electron-rich molecules = qualitative valence-bond approach via increased-valence structures /

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Bonding in electron-rich molecules/ by Richard D. Harcourt.
其他題名:	qualitative valence-bond approach via increased-valence structures /
作者:	Harcourt, Richard D.
出版者:	Cham :Springer International Publishing : : 2016.,
面頁冊數:	xv, 326 p. :ill., digital ; : 24 cm.;
Contained By:	Springer eBooks
標題:	Chemical bonds. -
電子資源:	http://dx.doi.org/10.1007/978-3-319-16676-6
ISBN:	9783319166766

Bonding in electron-rich molecules = qualitative valence-bond approach via increased-valence structures /
Harcourt, Richard D.

Bonding in electron-rich moleculesqualitative valence-bond approach via increased-valence structures /[electronic resource] :by Richard D. Harcourt. - 2nd ed. - Cham :Springer International Publishing :2016. - xv, 326 p. :ill., digital ;24 cm. - Lecture notes in chemistry,v.900342-4901 ;. - Lecture notes in chemistry ;v.78..

From the Contents: Atomic Orbitals, Electron Spin, Linear Combinations -- Pauling '3-Electron Bonds', 4-Electron 3-Centre Bonding, and the Need for an 'Increased Valence' Theory -- Wave-Functions and Valence-Bond Structures for 1-Electron Bonds, Electron-Pair Bonds, Pauling '3-Electron Bonds' and 'No Bonds' -- Valence-Bond Structures for Some Diatomic Molecules.

This second edition was updated to include some of the recent developments, such as "increased-valence" structures for 3-electron-3-centre bonding, benzene, electron conduction and reaction mechanisms, spiral chain O4 polymers and recoupled-pair bonding. The author provides qualitative molecular orbital and valence-bond descriptions of the electronic structures for primarily electron-rich molecules, with strong emphasis given to the valence-bond approach that uses "increased-valence" structures. He describes how "long-bond" Lewis structures as well as standard Lewis structures are incorporated into "increased-valence" structures for electron-rich molecules. "Increased-valence" structures involve more electrons in bonding than do their component Lewis structures, and are used to provide interpretations for molecular electronic structure, bond properties and reactivities. Attention is also given to Pauling "3-electron bonds", which are usually diatomic components of "increased-valence" structures for electron-rich molecules.

ISBN: 9783319166766

Standard No.: 10.1007/978-3-319-16676-6doiSubjects--Topical Terms:

654810
Chemical bonds.

LC Class. No.: QD461 / .H37 2015

Dewey Class. No.: 541.224

Bonding in electron-rich molecules = qualitative valence-bond approach via increased-valence structures /
LDR:02492nam a2200337 a 4500 001 860497
003 DE-He213
005 20160725142637.0
006 m d
007 cr nn 008maaau
008 170720s2016 gw s 0 eng d
020 $a 9783319166766 $q (electronic bk.)
020 $a 9783319166759 $q (paper)
024 7 $a 10.1007/978-3-319-16676-6 $2 doi
035 $a 978-3-319-16676-6
040 $a GP $c GP
041 0 $a eng
050 4 $a QD461 $b .H37 2015
072 7 $a PNRP $2 bicssc
072 7 $a SCI013050 $2 bisacsh
082 0 4 $a 541.224 $2 23
090 $a QD461 $b .H257 2016
100 1 $a Harcourt, Richard D. $3 1102167
245 1 0 $a Bonding in electron-rich molecules $h [electronic resource] : $b qualitative valence-bond approach via increased-valence structures / $c by Richard D. Harcourt.
250 $a 2nd ed.
260 $a Cham : $c 2016. $b Springer International Publishing : $b Imprint: Springer,
300 $a xv, 326 p. : $b ill., digital ; $c 24 cm.
490 1 $a Lecture notes in chemistry, $x 0342-4901 ; $v v.90
505 0 $a From the Contents: Atomic Orbitals, Electron Spin, Linear Combinations -- Pauling '3-Electron Bonds', 4-Electron 3-Centre Bonding, and the Need for an 'Increased Valence' Theory -- Wave-Functions and Valence-Bond Structures for 1-Electron Bonds, Electron-Pair Bonds, Pauling '3-Electron Bonds' and 'No Bonds' -- Valence-Bond Structures for Some Diatomic Molecules.
520 $a This second edition was updated to include some of the recent developments, such as "increased-valence" structures for 3-electron-3-centre bonding, benzene, electron conduction and reaction mechanisms, spiral chain O4 polymers and recoupled-pair bonding. The author provides qualitative molecular orbital and valence-bond descriptions of the electronic structures for primarily electron-rich molecules, with strong emphasis given to the valence-bond approach that uses "increased-valence" structures. He describes how "long-bond" Lewis structures as well as standard Lewis structures are incorporated into "increased-valence" structures for electron-rich molecules. "Increased-valence" structures involve more electrons in bonding than do their component Lewis structures, and are used to provide interpretations for molecular electronic structure, bond properties and reactivities. Attention is also given to Pauling "3-electron bonds", which are usually diatomic components of "increased-valence" structures for electron-rich molecules.
650 0 $a Chemical bonds. $3 654810
650 1 4 $a Chemistry. $3 593913
650 2 4 $a Theoretical and Computational Chemistry. $3 670313
650 2 4 $a Atomic/Molecular Structure and Spectra. $3 783942
650 2 4 $a Organic Chemistry. $3 673440
710 2 $a SpringerLink (Online service) $3 593884
773 0 $t Springer eBooks
830 0 $a Lecture notes in chemistry ; $v v.78. $3 888096
856 4 0 $u http://dx.doi.org/10.1007/978-3-319-16676-6
950 $a Chemistry and Materials Science (Springer-11644)