國立虎尾科技大學 |

Supported layered double hydroxides as CO2 adsorbents for sorption-enhanced H2 production

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Supported layered double hydroxides as CO2 adsorbents for sorption-enhanced H2 production/ by Diana Iruretagoyena Ferrer.
Author:	Ferrer, Diana Iruretagoyena.
Published:	Cham :Springer International Publishing : : 2016.,
Description:	xxxvii, 209 p. :ill., digital ; : 24 cm.;
Contained By:	Springer eBooks
Subject:	Layered double hydroxides. -
Online resource:	http://dx.doi.org/10.1007/978-3-319-41276-4
ISBN:	9783319412764

Supported layered double hydroxides as CO2 adsorbents for sorption-enhanced H2 production
Ferrer, Diana Iruretagoyena.

Supported layered double hydroxides as CO2 adsorbents for sorption-enhanced H2 production[electronic resource] /by Diana Iruretagoyena Ferrer. - Cham :Springer International Publishing :2016. - xxxvii, 209 p. :ill., digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

Introduction -- Literature Review -- Experimental Methods -- Layered Double Hydroxides Supported on Multi-Walled Carbon Nanotubes -- Layered Double Hydroxides Supported on Graphene Oxide for CO2 Adsorption -- Influence of Alkali Metals on Layered Double Hydroxides Supported on Graphene Oxide for CO2 Adsorption -- CO2 Adsorption on Unsupported and Graphene Oxide Supported Layered Double Hydroxides in a Fixed-Bed -- Sorption-Enhanced Methanol-to-Shift for H2 Production: Thermodynamics and Catalyst Selection -- Conclusions and Future Work.

This thesis presents a combination of material synthesis and characterization with process modeling. In it, the CO2 adsorption properties of hydrotalcites are enhanced through the production of novel supported hybrids (carbon nanotubes and graphene oxide) and the promotion with alkali metals. Hydrogen is regarded as a sustainable energy carrier, since the end users produce no carbon emissions. However, given that most of the hydrogen produced worldwide comes from fossil fuels, its potential as a carbon-free alternative depends on the ability to capture the carbon dioxide released during manufacture. Sorption-enhanced hydrogen production, in which CO2 is removed as it is formed, can make a major contribution to achieving this. The challenge is to find solid adsorbents with sufficient CO2 capacity that can work in the right temperature window over repeated adsorption-desorption cycles. The book presents a highly detailed characterization of the materials, together with an accurate measurement of their adsorption properties under dry conditions and in the presence of steam. It demonstrates that even small quantities of graphene oxide provide superior thermal stability to hydrotalcites due to their compatible layered structure, making them well suited as volume-efficient adsorbents for CO2. Lastly, it identifies suitable catalysts for the overall sorption-enhanced water gas shift process.

ISBN: 9783319412764

Standard No.: 10.1007/978-3-319-41276-4doiSubjects--Topical Terms:

1111602
Layered double hydroxides.

LC Class. No.: QD474 / .F47 2016

Dewey Class. No.: 541.2242

Supported layered double hydroxides as CO2 adsorbents for sorption-enhanced H2 production
LDR:02967nam a2200325 a 4500 001 865823
003 DE-He213
005 20160715041927.0
006 m d
007 cr nn 008maaau
008 170720s2016 gw s 0 eng d
020 $a 9783319412764 $q (electronic bk.)
020 $a 9783319412757 $q (paper)
024 7 $a 10.1007/978-3-319-41276-4 $2 doi
035 $a 978-3-319-41276-4
040 $a GP $c GP
041 0 $a eng
050 4 $a QD474 $b .F47 2016
072 7 $a THX $2 bicssc
072 7 $a TEC031010 $2 bisacsh
082 0 4 $a 541.2242 $2 23
090 $a QD474 $b .F385 2016
100 1 $a Ferrer, Diana Iruretagoyena. $3 1111601
245 1 0 $a Supported layered double hydroxides as CO2 adsorbents for sorption-enhanced H2 production $h [electronic resource] / $c by Diana Iruretagoyena Ferrer.
260 $a Cham : $c 2016. $b Springer International Publishing : $b Imprint: Springer,
300 $a xxxvii, 209 p. : $b ill., digital ; $c 24 cm.
490 1 $a Springer theses, $x 2190-5053
505 0 $a Introduction -- Literature Review -- Experimental Methods -- Layered Double Hydroxides Supported on Multi-Walled Carbon Nanotubes -- Layered Double Hydroxides Supported on Graphene Oxide for CO2 Adsorption -- Influence of Alkali Metals on Layered Double Hydroxides Supported on Graphene Oxide for CO2 Adsorption -- CO2 Adsorption on Unsupported and Graphene Oxide Supported Layered Double Hydroxides in a Fixed-Bed -- Sorption-Enhanced Methanol-to-Shift for H2 Production: Thermodynamics and Catalyst Selection -- Conclusions and Future Work.
520 $a This thesis presents a combination of material synthesis and characterization with process modeling. In it, the CO2 adsorption properties of hydrotalcites are enhanced through the production of novel supported hybrids (carbon nanotubes and graphene oxide) and the promotion with alkali metals. Hydrogen is regarded as a sustainable energy carrier, since the end users produce no carbon emissions. However, given that most of the hydrogen produced worldwide comes from fossil fuels, its potential as a carbon-free alternative depends on the ability to capture the carbon dioxide released during manufacture. Sorption-enhanced hydrogen production, in which CO2 is removed as it is formed, can make a major contribution to achieving this. The challenge is to find solid adsorbents with sufficient CO2 capacity that can work in the right temperature window over repeated adsorption-desorption cycles. The book presents a highly detailed characterization of the materials, together with an accurate measurement of their adsorption properties under dry conditions and in the presence of steam. It demonstrates that even small quantities of graphene oxide provide superior thermal stability to hydrotalcites due to their compatible layered structure, making them well suited as volume-efficient adsorbents for CO2. Lastly, it identifies suitable catalysts for the overall sorption-enhanced water gas shift process.
650 0 $a Layered double hydroxides. $3 1111602
650 1 4 $a Energy. $3 784773
650 2 4 $a Renewable and Green Energy. $3 683875
650 2 4 $a Industrial Chemistry/Chemical Engineering. $3 671153
650 2 4 $a Catalysis. $3 673438
650 2 4 $a Characterization and Evaluation of Materials. $3 674449
710 2 $a SpringerLink (Online service) $3 593884
773 0 $t Springer eBooks
830 0 $a Springer theses. $3 831604
856 4 0 $u http://dx.doi.org/10.1007/978-3-319-41276-4
950 $a Energy (Springer-40367)