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Quantitative infrared spectroscopy f...
~
Hasegawa, Takeshi.
Quantitative infrared spectroscopy for understanding of a condensed matter
Record Type:
Language materials, printed : Monograph/item
Title/Author:
Quantitative infrared spectroscopy for understanding of a condensed matter/ by Takeshi Hasegawa.
Author:
Hasegawa, Takeshi.
Published:
Tokyo :Springer Japan : : 2017.,
Description:
xi, 200 p. :ill. (some col.), digital ; : 24 cm.;
Contained By:
Springer eBooks
Subject:
Infrared spectroscopy. -
Online resource:
http://dx.doi.org/10.1007/978-4-431-56493-5
ISBN:
9784431564935
Quantitative infrared spectroscopy for understanding of a condensed matter
Hasegawa, Takeshi.
Quantitative infrared spectroscopy for understanding of a condensed matter
[electronic resource] /by Takeshi Hasegawa. - Tokyo :Springer Japan :2017. - xi, 200 p. :ill. (some col.), digital ;24 cm.
Infrared spectroscopy as a vibrational spectroscopy -- Normal modes -- Light absorption by a molecule: 1. Understanding by quantum mechanical approach -- Selection rule of IR spectroscopy -- Light absorption by a molecule: 2. Understanding by electrodynamical approach -- Fundamentals of FT-IR -- Two representations of spectra: Time- and frequency-domain representations -- Fourier transform relationship -- Introduction of Michaelson interferometer -- Representative detectors -- Sampling techniques -- Surface analysis using FT-IR -- Boundary conditions in electrodynamics -- Thin-film approximation -- Surface selection rules for surface spectroscopies -- Chemometrics for FT-IR -- Limitation of Beer's law -- Expansion of Beer's law: CLS regression -- Inverse Beer's law: ILS regression -- Mathematical expansion of CLS: PCA -- Merge of ILS and PCA: PCR -- Independent residual terms: PLS.
This book is intended to provide a course of infrared spectroscopy for quantitative analysis, covering both bulk matter and surface/interface analyses. Although the technology of Fourier transform infrared (FT-IR) spectroscopy was established many years ago, the full potential of infrared spectroscopy has not been properly recognized, and its intrinsic potential is still put aside. FT-IR has outstandingly useful characteristics, however, represented by the high sensitivity for monolayer analysis, highly reliable quantitativity, and reproducibility, which are quite suitable for surface and interface analysis. Because infrared spectroscopy provides rich chemical information--for example, hydrogen bonding, molecular conformation, orientation, aggregation, and crystallinity--FT-IR should be the first choice of chemical analysis in a laboratory. In this book, various analytical techniques and basic knowledge of infrared spectroscopy are described in a uniform manner. In particular, techniques for quantitative understanding are particularly focused for the reader's convenience.
ISBN: 9784431564935
Standard No.: 10.1007/978-4-431-56493-5doiSubjects--Topical Terms:
873887
Infrared spectroscopy.
LC Class. No.: QD96.I5
Dewey Class. No.: 543.57
Quantitative infrared spectroscopy for understanding of a condensed matter
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Infrared spectroscopy as a vibrational spectroscopy -- Normal modes -- Light absorption by a molecule: 1. Understanding by quantum mechanical approach -- Selection rule of IR spectroscopy -- Light absorption by a molecule: 2. Understanding by electrodynamical approach -- Fundamentals of FT-IR -- Two representations of spectra: Time- and frequency-domain representations -- Fourier transform relationship -- Introduction of Michaelson interferometer -- Representative detectors -- Sampling techniques -- Surface analysis using FT-IR -- Boundary conditions in electrodynamics -- Thin-film approximation -- Surface selection rules for surface spectroscopies -- Chemometrics for FT-IR -- Limitation of Beer's law -- Expansion of Beer's law: CLS regression -- Inverse Beer's law: ILS regression -- Mathematical expansion of CLS: PCA -- Merge of ILS and PCA: PCR -- Independent residual terms: PLS.
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This book is intended to provide a course of infrared spectroscopy for quantitative analysis, covering both bulk matter and surface/interface analyses. Although the technology of Fourier transform infrared (FT-IR) spectroscopy was established many years ago, the full potential of infrared spectroscopy has not been properly recognized, and its intrinsic potential is still put aside. FT-IR has outstandingly useful characteristics, however, represented by the high sensitivity for monolayer analysis, highly reliable quantitativity, and reproducibility, which are quite suitable for surface and interface analysis. Because infrared spectroscopy provides rich chemical information--for example, hydrogen bonding, molecular conformation, orientation, aggregation, and crystallinity--FT-IR should be the first choice of chemical analysis in a laboratory. In this book, various analytical techniques and basic knowledge of infrared spectroscopy are described in a uniform manner. In particular, techniques for quantitative understanding are particularly focused for the reader's convenience.
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Chemistry and Materials Science (Springer-11644)
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