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Rheology and microfluidic flows of a...
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ProQuest Information and Learning Co.
Rheology and microfluidic flows of a cationic surfactant and hydrotropic salt mixture.
紀錄類型:
書目-語言資料,手稿 : Monograph/item
正題名/作者:
Rheology and microfluidic flows of a cationic surfactant and hydrotropic salt mixture./
作者:
Zhao, Ya.
面頁冊數:
1 online resource (152 pages)
附註:
Source: Dissertation Abstracts International, Volume: 78-04(E), Section: B.
Contained By:
Dissertation Abstracts International78-04B(E).
標題:
Mechanical engineering. -
電子資源:
click for full text (PQDT)
ISBN:
9781369171242
Rheology and microfluidic flows of a cationic surfactant and hydrotropic salt mixture.
Zhao, Ya.
Rheology and microfluidic flows of a cationic surfactant and hydrotropic salt mixture.
- 1 online resource (152 pages)
Source: Dissertation Abstracts International, Volume: 78-04(E), Section: B.
Thesis (Ph.D.)
Includes bibliographical references
The widespread use of wormlike micellar solutions is commonly found in household items such as cosmetic products, industrial fluids used in enhanced oil recovery and as drag reducing agents, and in biological applications such as drug delivery and biosensors. Despite their extensive use, there are still many details about the microscopic micellar structure and the mechanisms by which wormlike micelles form under flow that are not clearly understood. We focused on studying an aqueous micellar solutions of cationic surfactant cetyltrimethylammonium bromide (CTAB) and organic hydrotropic salt 3-hydroxy naphthalene-2-carboxylate (SHNC), including linear and nonlinear rheological characterizations, flow instabilities of CTAB/SHNC solution around microfluidic cylinders. The strong hydrophobicity and naphthalene structure present in the SHNC induces significant growth of CTAB wormlike micelles and promotes stable micellar network formation. We correlated its rich rheological behavior with structural transitions of the micelle network under different deformation histories and temperature variations. Since microfluidic devices provide a versatile platform to study wormlike micellar solutions under various flow conditions and confined geometry, we are able to showcase that the influence of spatial confinement and moderate hydrodynamic forces present in the microfluidic device can give rise to a host of possibilities of microstructural rearrangements and interesting flow phenomena.
Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2018
Mode of access: World Wide Web
ISBN: 9781369171242Subjects--Topical Terms:
557493
Mechanical engineering.
Index Terms--Genre/Form:
554714
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The widespread use of wormlike micellar solutions is commonly found in household items such as cosmetic products, industrial fluids used in enhanced oil recovery and as drag reducing agents, and in biological applications such as drug delivery and biosensors. Despite their extensive use, there are still many details about the microscopic micellar structure and the mechanisms by which wormlike micelles form under flow that are not clearly understood. We focused on studying an aqueous micellar solutions of cationic surfactant cetyltrimethylammonium bromide (CTAB) and organic hydrotropic salt 3-hydroxy naphthalene-2-carboxylate (SHNC), including linear and nonlinear rheological characterizations, flow instabilities of CTAB/SHNC solution around microfluidic cylinders. The strong hydrophobicity and naphthalene structure present in the SHNC induces significant growth of CTAB wormlike micelles and promotes stable micellar network formation. We correlated its rich rheological behavior with structural transitions of the micelle network under different deformation histories and temperature variations. Since microfluidic devices provide a versatile platform to study wormlike micellar solutions under various flow conditions and confined geometry, we are able to showcase that the influence of spatial confinement and moderate hydrodynamic forces present in the microfluidic device can give rise to a host of possibilities of microstructural rearrangements and interesting flow phenomena.
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