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Structure-Property Relationships in ...
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Princeton University.
Structure-Property Relationships in Novel Materials
紀錄類型:
書目-語言資料,手稿 : Monograph/item
正題名/作者:
Structure-Property Relationships in Novel Materials/
作者:
Seibel, Elizabeth M.
面頁冊數:
1 online resource (180 pages)
附註:
Source: Dissertation Abstracts International, Volume: 78-11(E), Section: B.
標題:
Organic chemistry. -
電子資源:
click for full text (PQDT)
ISBN:
9780355039481
Structure-Property Relationships in Novel Materials
Seibel, Elizabeth M.
Structure-Property Relationships in Novel Materials
- 1 online resource (180 pages)
Source: Dissertation Abstracts International, Volume: 78-11(E), Section: B.
Thesis (Ph.D.)--Princeton University, 2017.
Includes bibliographical references
Part I. Frustrated Magnetism and Deintercalation of Honeycomb Oxides -- Part II. Electron-Precise Gold Intermetallics.
This thesis is a study of the structure-property relationships of novel materials, broken into two major parts. The first part, "Part I: Frustrated Magnetism and Deintercalation of Honeycomb Oxides" explores new, layered nickel oxides and their properties, specifically the synthesis, structure, magnetism, and applications of the Na3Ni 2BiO6-NaNi2BiO6-NaNi2BiO 6•1.7H2O system. These phases are of interest to the solid-state and physics communities because they display frustrated magnetism on a hexagonal lattice. Chapter 3 explores the chemistry and physics of Na 3Ni2BiO6; Chapter 4 then discusses its chemical deintercalation and subsequent hydration to form the NaNi2BiO 6-NaNi2BiO6•1.7H2O system. These phases are examples of sought-after spin-1/2 systems on a hexagonal lattice.
Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2018
Mode of access: World Wide Web
ISBN: 9780355039481Subjects--Topical Terms:
1148722
Organic chemistry.
Index Terms--Genre/Form:
554714
Electronic books.
Structure-Property Relationships in Novel Materials
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Source: Dissertation Abstracts International, Volume: 78-11(E), Section: B.
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Adviser: Robert J. Cava.
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Thesis (Ph.D.)--Princeton University, 2017.
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Includes bibliographical references
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Part I. Frustrated Magnetism and Deintercalation of Honeycomb Oxides -- Part II. Electron-Precise Gold Intermetallics.
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This thesis is a study of the structure-property relationships of novel materials, broken into two major parts. The first part, "Part I: Frustrated Magnetism and Deintercalation of Honeycomb Oxides" explores new, layered nickel oxides and their properties, specifically the synthesis, structure, magnetism, and applications of the Na3Ni 2BiO6-NaNi2BiO6-NaNi2BiO 6•1.7H2O system. These phases are of interest to the solid-state and physics communities because they display frustrated magnetism on a hexagonal lattice. Chapter 3 explores the chemistry and physics of Na 3Ni2BiO6; Chapter 4 then discusses its chemical deintercalation and subsequent hydration to form the NaNi2BiO 6-NaNi2BiO6•1.7H2O system. These phases are examples of sought-after spin-1/2 systems on a hexagonal lattice.
520
$a
The second part of this thesis, "Part II: Electron-Precise Gold Intermetallics" explores novel, electron-precise intermetallics in the Lanthanide-gold-pnictide ternary system. The chemistry of gold-containing solids has not been well-studied despite gold's unusual physics, motivating the study. There are three new families discussed herein. The first, found in Chapter 7, is of the type LnAuSb (Ln = Lanthanide) which are new Dirac semimetals. The work illustrates a chemical design principle that can be used to predict new Dirac Semimetals, which is important given that the field of topological materials is rapidly growing. Chapter 8 discusses materials of the type LnAuBi2, which are layered intermetallics with a high degree of magnetic anisotropy. Finally, Chapter 9 explores new phases of the form Ln 3Au3Bi4. These materials are semiconductors with high Seebeck coefficients at room temperature, indicating their potential for use as thermoelectric materials.
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2018
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Mode of access: World Wide Web
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click for full text (PQDT)
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