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Velocity-map Imaging Photoelectron Spectroscopy of Small Molecular Anions.

Record Type:	Language materials, manuscript : Monograph/item
Title/Author:	Velocity-map Imaging Photoelectron Spectroscopy of Small Molecular Anions./
Author:	Oliveira, Allan Maple de.
Description:	1 online resource (328 pages)
Notes:	Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.
Contained By:	Dissertation Abstracts International79-09B(E).
Subject:	Physical chemistry. -
Online resource:	click for full text (PQDT)
ISBN:	9780355964868

Velocity-map Imaging Photoelectron Spectroscopy of Small Molecular Anions.
Oliveira, Allan Maple de.

Velocity-map Imaging Photoelectron Spectroscopy of Small Molecular Anions. - 1 online resource (328 pages)

Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.

Thesis (Ph.D.)--University of Colorado at Boulder, 2018.

Includes bibliographical references

Gas phase anion photoelectron spectroscopy presents an opportunity for investigating molecules that are inaccessible by other experimental techniques, by providing data on the structure, reactivity and energetics of short-lived radicals and transition state species. Our recent development of a novel, plasma entrainment source of cold, weakly-bound anions opens a door to new exotic species to be investigated. In this thesis, I explore the capabilities of photoelectron spectroscopy and its application to small exotic molecular anions, while further developing and employing the novel dual-valve ion source.

Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2018

Mode of access: World Wide Web

ISBN: 9780355964868Subjects--Topical Terms:

1148725
Physical chemistry.
Index Terms--Genre/Form:

554714
Electronic books.

Velocity-map Imaging Photoelectron Spectroscopy of Small Molecular Anions.
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100 1 $a Oliveira, Allan Maple de. $3 1192031
245 1 0 $a Velocity-map Imaging Photoelectron Spectroscopy of Small Molecular Anions.
264 0 $c 2018
300 $a 1 online resource (328 pages)
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500 $a Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.
500 $a Advisers: W. Carl Lineberger; Veronica M. Bierbaum.
502 $a Thesis (Ph.D.)--University of Colorado at Boulder, 2018.
504 $a Includes bibliographical references
520 $a Gas phase anion photoelectron spectroscopy presents an opportunity for investigating molecules that are inaccessible by other experimental techniques, by providing data on the structure, reactivity and energetics of short-lived radicals and transition state species. Our recent development of a novel, plasma entrainment source of cold, weakly-bound anions opens a door to new exotic species to be investigated. In this thesis, I explore the capabilities of photoelectron spectroscopy and its application to small exotic molecular anions, while further developing and employing the novel dual-valve ion source.
520 $a The thesis begins with a brief history of photoelectron spectroscopy, followed by a description of the experimental apparatus. The first anion studied using the new anion source is the weakly bound methide anion (CH3 --). This experiment provides the first measurement of the inversion splitting of this simple pyramidal carbanion. The precise measurement of the electron affinity (EA) of the methyl radical provides accurate measurements of the gas phase acidity of methane, which defines the acidity scale of hydrocarbons.
520 $a I then explore the spectroscopy of the atmospherically significant HONO molecule, via photoelectron spectroscopy of the open-shelled HONO-- radical anion. HONO-- is produced in a reaction between OH-- and NO, a feat accomplished in the cold, collision-rich environment of the novel anion source. This experiment allows for the first measurement of the EA of HONO and the excitation energy to its lowest excited state, the triplet, which is inaccessible by most spectroscopic techniques.
520 $a Next, I investigate of the electronic structure of singly substituted alkoxy radicals. The new dual-valve source allowed for controlled synthesis of hydroxymethoxide and aminomethoxide. The selective substitution allows us to probe what effect the substituting group has on the electronic structure of alkoxy radicals, leading to a correlation between the substituent group's electronegativity and the EAs and excited state energies of the radicals.
520 $a Finally, I investigate the biologically relevant 7-azaindole and its hydrogen bonded dimer. The photoelectron spectrum of 7-azaindolide provides a measurement of the EA of the 7-azaindolyl radical and reveals an unexpected behavior of the spectrum, where most of the observed signal derives from a process other than direct photodetachment.
533 $a Electronic reproduction. $b Ann Arbor, Mich. : $c ProQuest, $d 2018
538 $a Mode of access: World Wide Web
650 4 $a Physical chemistry. $3 1148725
650 4 $a Chemistry. $3 593913
650 4 $a Physics. $3 564049
655 7 $a Electronic books. $2 local $3 554714
690 $a 0494
690 $a 0485
690 $a 0605
710 2 $a ProQuest Information and Learning Co. $3 1178819
710 2 $a University of Colorado at Boulder. $b Chemistry. $3 1192032
773 0 $t Dissertation Abstracts International $g 79-09B(E).
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10745440 $z click for full text (PQDT)