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Catalytic Asymmetric Desymmetrisatio...
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Yi, Yi.
Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization.
紀錄類型:
書目-語言資料,手稿 : Monograph/item
正題名/作者:
Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization./
作者:
Yi, Yi.
面頁冊數:
1 online resource (318 pages)
附註:
Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.
Contained By:
Dissertation Abstracts International79-09B(E).
標題:
Organic chemistry. -
電子資源:
click for full text (PQDT)
ISBN:
9780355890662
Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization.
Yi, Yi.
Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization.
- 1 online resource (318 pages)
Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.
Thesis (Ph.D.)--Michigan State University, 2018.
Includes bibliographical references
My doctorate research work with professor Borhan is mainly focused on developing new asymmetric halofunctionalization reactions. Chapter 1 describes the catalytic asymmetric desymmetrisation of dienes via chlorocyclization. Chapter 2 describes the kinetic resolution of propargyl amides via chlorocyclization. Both desymmetrisation and kinetic resolution using cinchona alkaloid (DHQD) 2PHAL as catalyst afford good diastereoselectivity and enantioselectivity. Chapter 3 discloses efforts to develop asymmetric ipso-halocyclization via dearomatization of phenol derivatives. Chapter 4 describes a novel and practical method to access N,O-acetals using commercially available XtalFluor-ERTM as catalyst.
Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2018
Mode of access: World Wide Web
ISBN: 9780355890662Subjects--Topical Terms:
1148722
Organic chemistry.
Index Terms--Genre/Form:
554714
Electronic books.
Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization.
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Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.
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My doctorate research work with professor Borhan is mainly focused on developing new asymmetric halofunctionalization reactions. Chapter 1 describes the catalytic asymmetric desymmetrisation of dienes via chlorocyclization. Chapter 2 describes the kinetic resolution of propargyl amides via chlorocyclization. Both desymmetrisation and kinetic resolution using cinchona alkaloid (DHQD) 2PHAL as catalyst afford good diastereoselectivity and enantioselectivity. Chapter 3 discloses efforts to develop asymmetric ipso-halocyclization via dearomatization of phenol derivatives. Chapter 4 describes a novel and practical method to access N,O-acetals using commercially available XtalFluor-ERTM as catalyst.
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