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Structural transformations in dilute...
~
Zelaya-Rincon, Blanca.
Structural transformations in diluted micellar and lamellar systems.
紀錄類型:
書目-語言資料,手稿 : Monograph/item
正題名/作者:
Structural transformations in diluted micellar and lamellar systems./
作者:
Zelaya-Rincon, Blanca.
面頁冊數:
1 online resource (42 pages)
附註:
Source: Masters Abstracts International, Volume: 57-01.
Contained By:
Masters Abstracts International57-01(E).
標題:
Chemical engineering. -
電子資源:
click for full text (PQDT)
ISBN:
9780355469851
Structural transformations in diluted micellar and lamellar systems.
Zelaya-Rincon, Blanca.
Structural transformations in diluted micellar and lamellar systems.
- 1 online resource (42 pages)
Source: Masters Abstracts International, Volume: 57-01.
Thesis (M.S.)--University of Rhode Island, 2018.
Includes bibliographical references
The role of dilution by artificial hard water on nanostructures present in body wash samples provided by Procter and Gamble were investigated using time-resolved cryogenic transmission electron microscopy (cryo-TEM). Samples with and without perfume were examined at 10X, 20X, and 50X dilution. Micellar samples transformed to mostly unilamellar vesicles at 50X dilution, in contrast to the micelle to monomer transition seen in typical samples. At lower dilutions, a change in morphology from spherical to wormlike micelles was observed. For lamellar samples, lower dilution ratios show tightly packed multilamellar vesicles, while higher dilution ratios show more dispersed vesicles with less bilayers. Nanostructural transformations upon dilution were attributed to changes in curvature/packing parameters, which occurred due to dilution with hard water and addition of perfume. The systems experience changes in curvature in order to maintain equilibrium. Also, the addition of perfume in the lamellar samples caused an increase in the number of bilayers present in multilamellar vesicles, because of its role in increasing the packing parameter in the system.
Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2018
Mode of access: World Wide Web
ISBN: 9780355469851Subjects--Topical Terms:
555952
Chemical engineering.
Index Terms--Genre/Form:
554714
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The role of dilution by artificial hard water on nanostructures present in body wash samples provided by Procter and Gamble were investigated using time-resolved cryogenic transmission electron microscopy (cryo-TEM). Samples with and without perfume were examined at 10X, 20X, and 50X dilution. Micellar samples transformed to mostly unilamellar vesicles at 50X dilution, in contrast to the micelle to monomer transition seen in typical samples. At lower dilutions, a change in morphology from spherical to wormlike micelles was observed. For lamellar samples, lower dilution ratios show tightly packed multilamellar vesicles, while higher dilution ratios show more dispersed vesicles with less bilayers. Nanostructural transformations upon dilution were attributed to changes in curvature/packing parameters, which occurred due to dilution with hard water and addition of perfume. The systems experience changes in curvature in order to maintain equilibrium. Also, the addition of perfume in the lamellar samples caused an increase in the number of bilayers present in multilamellar vesicles, because of its role in increasing the packing parameter in the system.
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click for full text (PQDT)
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