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Multifunctional molecular magnets based on octacyanidometalates

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Multifunctional molecular magnets based on octacyanidometalates/ by Kenta Imoto.
Author:	Imoto, Kenta.
Published:	Singapore :Springer Singapore : : 2017.,
Description:	xiii, 89 p. :ill., digital ; : 24 cm.;
Contained By:	Springer eBooks
Subject:	Magnetic materials. -
Online resource:	http://dx.doi.org/10.1007/978-981-10-6135-6
ISBN:	9789811061356

Multifunctional molecular magnets based on octacyanidometalates
Imoto, Kenta.

Multifunctional molecular magnets based on octacyanidometalates[electronic resource] /by Kenta Imoto. - Singapore :Springer Singapore :2017. - xiii, 89 p. :ill., digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

1. Introduction -- 2. Light-induced Spin-crossover Magnetism in an Iron Octacyanidoniobate-based Assembly -- 3. Two-step Spin-crossover and Photo-induced Spin-crossover in an Iron Octacyanidoniobate-based Assembly -- 4. Observation of Coexistence of Super-ionic Conductivity and Metamagnetism in a Manganese Octacyanidoniobate-based Assembly -- 5. Summary and Perspective.

This thesis demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies, and as such appeals to readers in the field of materials science. The utilization of octacyanidometalates as building blocks enables the observation of (i) photo-induced magnetization due to a light-induced spin-crossover in an iron octacyanidoniobate-based assembly, (ii) photo-induced magnetization with a two-step spin-crossover behavior in an iron octacyanidoniobate-based material, and (iii) the coexistence of super-ionic conductivity and metamagnetism in a manganese-octacyanoniobate system. These multi-functionalities are achieved by incorporating a spin-crossover moiety or a hydrogen-bonding network into a cyanido-bridged network structure with a strong magnetic interaction. In particular, in light-induced spin-crossover magnets, a magnetically non-ordered state can be altered to a magnetically ordered state by photo-irradiation, which is one of the attractive mechanisms for novel optical switching devices.

ISBN: 9789811061356

Standard No.: 10.1007/978-981-10-6135-6doiSubjects--Topical Terms:

639418
Magnetic materials.

LC Class. No.: QC765

Dewey Class. No.: 620.11297

Multifunctional molecular magnets based on octacyanidometalates
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505 0 $a 1. Introduction -- 2. Light-induced Spin-crossover Magnetism in an Iron Octacyanidoniobate-based Assembly -- 3. Two-step Spin-crossover and Photo-induced Spin-crossover in an Iron Octacyanidoniobate-based Assembly -- 4. Observation of Coexistence of Super-ionic Conductivity and Metamagnetism in a Manganese Octacyanidoniobate-based Assembly -- 5. Summary and Perspective.
520 $a This thesis demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies, and as such appeals to readers in the field of materials science. The utilization of octacyanidometalates as building blocks enables the observation of (i) photo-induced magnetization due to a light-induced spin-crossover in an iron octacyanidoniobate-based assembly, (ii) photo-induced magnetization with a two-step spin-crossover behavior in an iron octacyanidoniobate-based material, and (iii) the coexistence of super-ionic conductivity and metamagnetism in a manganese-octacyanoniobate system. These multi-functionalities are achieved by incorporating a spin-crossover moiety or a hydrogen-bonding network into a cyanido-bridged network structure with a strong magnetic interaction. In particular, in light-induced spin-crossover magnets, a magnetically non-ordered state can be altered to a magnetically ordered state by photo-irradiation, which is one of the attractive mechanisms for novel optical switching devices.
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