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Assembled lanthanide complexes with advanced photophysical properties

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Assembled lanthanide complexes with advanced photophysical properties/ by Yuichi Hirai.
Author:	Hirai, Yuichi.
Published:	Singapore :Springer Singapore : : 2018.,
Description:	xv, 106 p. :ill., digital ; : 24 cm.;
Contained By:	Springer eBooks
Subject:	Rare earth metals. -
Online resource:	http://dx.doi.org/10.1007/978-981-10-8932-9
ISBN:	9789811089329

Assembled lanthanide complexes with advanced photophysical properties
Hirai, Yuichi.

Assembled lanthanide complexes with advanced photophysical properties[electronic resource] /by Yuichi Hirai. - Singapore :Springer Singapore :2018. - xv, 106 p. :ill., digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

General introduction -- Luminescent lanthanide coordination polymers with densely-packed structures for high energy transfer efficiency -- Luminescent lanthanide-mixed coordination polymers for tunable temperature-sensitivity -- Construction of luminescent lanthanide coordination glass -- Amorphous formability and temperature-sensitive luminescence of lanthanide coordination glasses -- Triboluminescence of lanthanide coordination polymers -- Summary.

This thesis provides essential information on the systematic design of assembled lanthanide complexes for functional luminescent materials. It discusses the relationships between assembled structures and photo, thermal, and mechanical properties on the basis of crystallography, spectroscopy, and thermodynamics. The described guidelines for assembled structures will be extremely valuable, both for industrial applications and for readers' fundamental understanding of solid-state photophysics and materials chemistry. Luminescent lanthanide complexes are promising candidates for lighting devices, lasers, and bio-probes owing to their line-like and long-lived emission arising from characteristic 4f-4f transitions. Low-vibrational and asymmetrical coordination structures around lanthanide ions have been introduced to achieve strong luminescence, using specific organic ligands. Recently, assembled lanthanide complexes including coordination polymers and metal organic frameworks have increasingly attracted attention as a new class of luminescent materials offering thermal stability and color tunability. However, improving the luminescence efficiencies of these compounds remains a challenge, and specific molecular designs to control assembled structures and yield additional physical properties have not been established. The author provides a group of bent-angled bridging ligands to boost photoluminescence efficiency, and successfully introduces for the first time glass formability and strong triboluminescence properties.

ISBN: 9789811089329

Standard No.: 10.1007/978-981-10-8932-9doiSubjects--Topical Terms:

700711
Rare earth metals.

LC Class. No.: QD172.R2 / H573 2018

Dewey Class. No.: 546.41

Assembled lanthanide complexes with advanced photophysical properties
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