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Assemblies of gold nanoparticles at liquid-liquid interfaces = from liquid optics to electrocatalysis /

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Assemblies of gold nanoparticles at liquid-liquid interfaces/ by Evgeny Smirnov.
Reminder of title:	from liquid optics to electrocatalysis /
Author:	Smirnov, Evgeny.
Published:	Cham :Springer International Publishing : : 2018.,
Description:	xx, 258 p. :ill., digital ; : 24 cm.;
Contained By:	Springer eBooks
Subject:	Self-assembly (Chemistry) -
Online resource:	http://dx.doi.org/10.1007/978-3-319-77914-0
ISBN:	9783319779140

Assemblies of gold nanoparticles at liquid-liquid interfaces = from liquid optics to electrocatalysis /
Smirnov, Evgeny.

Assemblies of gold nanoparticles at liquid-liquid interfacesfrom liquid optics to electrocatalysis /[electronic resource] :by Evgeny Smirnov. - Cham :Springer International Publishing :2018. - xx, 258 p. :ill., digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

Introduction -- Experimental and Instrumentation -- Self-assembly of Nanoparticles into Gold Metal Liquid-Like Droplets (MeLLDs) -- Optical properties of self-healing gold nanoparticle mirrors and filters at Liquid-Liquid interfaces -- Self-assembly of gold nanoparticles: low interfacial tensions -- Electrochemical investigation of nanofilms at liquid-liquid interface -- Electron transfer reactions and redox catalysis on gold nanofilms at soft interfaces -- Gold nanofilm redox electrocatalysis for oxygen reduction at soft interfaces -- Perspectives: from Colloidosomes through SERS to electrically driven Marangoni Shutters -- General conclusions.

This book is devoted to various aspects of self-assembly of gold nanoparticles at liquid-liquid interfaces and investigation of their properties. It covers primarily two large fields: (i) self-assembly of nanoparticles and optical properties of these assemblies; and (ii) the role of nanoparticles in redox electrocatalysis at liquid-liquid interfaces. The first part aroused from a long-lasting idea to manipulate adsorption of nanoparticles at liquid-liquid with an external electric field to form 'smart' mirrors and/or filters. Therefore, Chapters 3 to 5 are dedicated to explore fundamental aspects of charged nanoparticles self-assembly and to investigate optical properties (extinction and reflectance) in a through manner. Novel tetrathiafulvalene (TTF)-assisted method leads to self-assembly of nanoparticles into cm-scale nanofilms or, so-called, metal liquid-like droplets (MeLLDs) with remarkable optical properties. The second part (Chapters 6 to 8) clarifies the role of nanoparticles in interfacial electron transfer reactions. They demonstrate how nanoparticles are charged and discharged upon equilibration of Fermi levels with redox couples in solution and how it can be used to perform HER and ORR. Finally, chapter 9 gives a perspective outlook, including applications of suggested methods in fast, one-step preparation of colloidosomes, SERS substrates as well as pioneer studies on so-called Marangony-type shutters drive by the electric field.

ISBN: 9783319779140

Standard No.: 10.1007/978-3-319-77914-0doiSubjects--Topical Terms:

655661
Self-assembly (Chemistry)

LC Class. No.: QA475 / .S657 2018

Dewey Class. No.: 547.2

Assemblies of gold nanoparticles at liquid-liquid interfaces = from liquid optics to electrocatalysis /
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505 0 $a Introduction -- Experimental and Instrumentation -- Self-assembly of Nanoparticles into Gold Metal Liquid-Like Droplets (MeLLDs) -- Optical properties of self-healing gold nanoparticle mirrors and filters at Liquid-Liquid interfaces -- Self-assembly of gold nanoparticles: low interfacial tensions -- Electrochemical investigation of nanofilms at liquid-liquid interface -- Electron transfer reactions and redox catalysis on gold nanofilms at soft interfaces -- Gold nanofilm redox electrocatalysis for oxygen reduction at soft interfaces -- Perspectives: from Colloidosomes through SERS to electrically driven Marangoni Shutters -- General conclusions.
520 $a This book is devoted to various aspects of self-assembly of gold nanoparticles at liquid-liquid interfaces and investigation of their properties. It covers primarily two large fields: (i) self-assembly of nanoparticles and optical properties of these assemblies; and (ii) the role of nanoparticles in redox electrocatalysis at liquid-liquid interfaces. The first part aroused from a long-lasting idea to manipulate adsorption of nanoparticles at liquid-liquid with an external electric field to form 'smart' mirrors and/or filters. Therefore, Chapters 3 to 5 are dedicated to explore fundamental aspects of charged nanoparticles self-assembly and to investigate optical properties (extinction and reflectance) in a through manner. Novel tetrathiafulvalene (TTF)-assisted method leads to self-assembly of nanoparticles into cm-scale nanofilms or, so-called, metal liquid-like droplets (MeLLDs) with remarkable optical properties. The second part (Chapters 6 to 8) clarifies the role of nanoparticles in interfacial electron transfer reactions. They demonstrate how nanoparticles are charged and discharged upon equilibration of Fermi levels with redox couples in solution and how it can be used to perform HER and ORR. Finally, chapter 9 gives a perspective outlook, including applications of suggested methods in fast, one-step preparation of colloidosomes, SERS substrates as well as pioneer studies on so-called Marangony-type shutters drive by the electric field.
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