國立虎尾科技大學 |

Organic Photovoltaics Based on Solution Cast Polymers and Boron Subphthalocyanines - Hybrid Device Architectures Enabling Novel Material Combinations.

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Organic Photovoltaics Based on Solution Cast Polymers and Boron Subphthalocyanines - Hybrid Device Architectures Enabling Novel Material Combinations./
作者:	Nyikos, Stephanie Robin.
出版者:	Ann Arbor : ProQuest Dissertations & Theses, : 2018,
面頁冊數:	84 p.
附註:	Source: Masters Abstracts International, Volume: 58-03.
Contained By:	Masters Abstracts International58-03(E).
標題:	Chemical engineering. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10973996
ISBN:	9780438674585

Organic Photovoltaics Based on Solution Cast Polymers and Boron Subphthalocyanines - Hybrid Device Architectures Enabling Novel Material Combinations.
Nyikos, Stephanie Robin.

Organic Photovoltaics Based on Solution Cast Polymers and Boron Subphthalocyanines - Hybrid Device Architectures Enabling Novel Material Combinations. - Ann Arbor : ProQuest Dissertations & Theses, 2018 - 84 p.

Source: Masters Abstracts International, Volume: 58-03.

Thesis (M.A.S.)--University of Toronto (Canada), 2018.

Solution-cast films of crystalline electron donating poly(3,3"'-didodecylquaterthiophene) (PQT-12) were studied in pseudo-planar heterojunction (PPHJ) organic photovoltaic devices (OPVs) paired with boron subphthalocyanine (BsubPc) as the electron acceptor layer, and the effects of crystallinity domain size and layer thickness were investigated. Annealed, 10-20 nm films of intermediate-sized crystals were 40% more efficient than un-annealed PQT-12 layers and had comparable efficiency to their fullerene-based BHJ counterparts, demonstrating the ability of polymer|BsubPc PPHJ OPVs to accommodate highly crystalline polymers with a tendency to phase segregate and create devices with favorable electrical properties. These polymer|BsubPc PPHJs were further studied with the new amorphous copolymer electron donating material PBTZT-stat-BDTT-8. While optimized PPHJ devices of PBTZT-stat-BDTT-8|BsubPc had substantially lower efficiency than PBTZT-stat-BDTT-8|fullerene BHJs (which were free of morphological problems), they demonstrated comparable performance to their BHJ equivalents due to ideal morphology, presenting a pathway forward for OPV design of otherwise phase segregating polymer|BsubPc pairings.

ISBN: 9780438674585Subjects--Topical Terms:

555952
Chemical engineering.

Organic Photovoltaics Based on Solution Cast Polymers and Boron Subphthalocyanines - Hybrid Device Architectures Enabling Novel Material Combinations.
LDR:02241nam a2200313 4500 001 931705
005 20190716101636.5
008 190815s2018 ||||||||||||||||| ||eng d
020 $a 9780438674585
035 $a (MiAaPQ)AAI10973996
035 $a (MiAaPQ)toronto:18598
035 $a AAI10973996
040 $a MiAaPQ $c MiAaPQ
100 1 $a Nyikos, Stephanie Robin. $3 1213918
245 1 0 $a Organic Photovoltaics Based on Solution Cast Polymers and Boron Subphthalocyanines - Hybrid Device Architectures Enabling Novel Material Combinations.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2018
300 $a 84 p.
500 $a Source: Masters Abstracts International, Volume: 58-03.
500 $a Adviser: Timothy P. Bender.
502 $a Thesis (M.A.S.)--University of Toronto (Canada), 2018.
520 $a Solution-cast films of crystalline electron donating poly(3,3"'-didodecylquaterthiophene) (PQT-12) were studied in pseudo-planar heterojunction (PPHJ) organic photovoltaic devices (OPVs) paired with boron subphthalocyanine (BsubPc) as the electron acceptor layer, and the effects of crystallinity domain size and layer thickness were investigated. Annealed, 10-20 nm films of intermediate-sized crystals were 40% more efficient than un-annealed PQT-12 layers and had comparable efficiency to their fullerene-based BHJ counterparts, demonstrating the ability of polymer|BsubPc PPHJ OPVs to accommodate highly crystalline polymers with a tendency to phase segregate and create devices with favorable electrical properties. These polymer|BsubPc PPHJs were further studied with the new amorphous copolymer electron donating material PBTZT-stat-BDTT-8. While optimized PPHJ devices of PBTZT-stat-BDTT-8|BsubPc had substantially lower efficiency than PBTZT-stat-BDTT-8|fullerene BHJs (which were free of morphological problems), they demonstrated comparable performance to their BHJ equivalents due to ideal morphology, presenting a pathway forward for OPV design of otherwise phase segregating polymer|BsubPc pairings.
590 $a School code: 0779.
650 4 $a Chemical engineering. $3 555952
650 4 $a Materials science. $3 557839
650 4 $a Energy. $3 784773
690 $a 0542
690 $a 0794
690 $a 0791
710 2 $a University of Toronto (Canada). $b Chemical Engineering & Applied Chemistry. $3 1181092
773 0 $t Masters Abstracts International $g 58-03(E).
790 $a 0779
791 $a M.A.S.
792 $a 2018
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10973996