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Non-equilibrium Phenomena in Confined Soft Matter = Irreversible Adsorption, Physical Aging and Glass Transition at the Nanoscale /

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Non-equilibrium Phenomena in Confined Soft Matter/ edited by Simone Napolitano.
其他題名:	Irreversible Adsorption, Physical Aging and Glass Transition at the Nanoscale /
其他作者:	Napolitano, Simone.
面頁冊數:	VIII, 300 p. 131 illus., 71 illus. in color.online resource. :
Contained By:	Springer Nature eBook
標題:	Amorphous substances. -
電子資源:	https://doi.org/10.1007/978-3-319-21948-6
ISBN:	9783319219486

Non-equilibrium Phenomena in Confined Soft Matter = Irreversible Adsorption, Physical Aging and Glass Transition at the Nanoscale /
Non-equilibrium Phenomena in Confined Soft MatterIrreversible Adsorption, Physical Aging and Glass Transition at the Nanoscale /[electronic resource] :edited by Simone Napolitano. - 1st ed. 2015. - VIII, 300 p. 131 illus., 71 illus. in color.online resource. - Soft and Biological Matter,2213-1736. - Soft and Biological Matter,.

From the Contents: Kinetics of irreversible chain adsorption, new insights from experiments and simulations -- Structure and dynamics of adsorbed polymer layers -- An investigation of irreversibly adsorbed polymer layers via Local Dielectric Spectroscopy -- History dependent temporal changes of properties of thin polymer films.

This book presents cutting-edge experimental and computational results and provides comprehensive coverage on the impact of non-equilibrium structure and dynamics on the properties of soft matter confined to the nanoscale. The book is organized into three main sections: · Equilibration and physical aging: by treating non-equilibrium phenomena with the formal methodology of statistical physics in bulk, the analysis of the kinetics of equilibration sheds new light on the physical origin of the non-equilibrium character of thin polymer films. Both the impact of sample preparation and that of interfacial interactions are analyzed using a large set of experiments. A historical overview of the investigation of the non-equilibrium character of thin polymer films is also presented. Furthermore, the discussion focuses on how interfaces and geometrical confinement perturb the pathways and kinetics of equilibrations of soft glasses (a process of tremendous technological interest). · Irreversible adsorption: the formation of stable adsorbed layers occurs at timescales much larger than the time necessary to equilibrate soft matter in bulk. The question is posed as to whether this process could be considered as the driving force of equilibration. In this section, the investigation of the physics of irreversible chain adsorption is accompanied by a detailed analysis of the molecular dynamics, structure, morphology, and crystallization of adsorbed layers. · Glass transition and material properties: the discussion covers a broad range of non-equilibrium phenomena affecting different families of soft materials – polymers, low molecular weight glass formers, and liquid crystals. In these systems, geometrical confinement induces the formation of non-equilibrium phases, otherwise not achievable via processing of bulk samples. The examples illustrated in this section show how non-equilibrium phenomena can be exploited as innovative processing parameters to fabricate novel nanomaterials with improved performance. Finally, the differences between experiments performed under equilibrium conditions and temperature scans from equilibrium to non-equilibrium states at the nanoscale are discussed.

ISBN: 9783319219486

Standard No.: 10.1007/978-3-319-21948-6doiSubjects--Topical Terms:

769064
Amorphous substances.

LC Class. No.: QC176.8.A44

Dewey Class. No.: 530.41

Non-equilibrium Phenomena in Confined Soft Matter = Irreversible Adsorption, Physical Aging and Glass Transition at the Nanoscale /
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