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Functionalization of Carborane via Carboryne Intermediates

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Functionalization of Carborane via Carboryne Intermediates/ by Da Zhao.
作者:	Zhao, Da.
面頁冊數:	XVII, 170 p. 126 illus., 5 illus. in color.online resource. :
Contained By:	Springer Nature eBook
標題:	Organic chemistry. -
電子資源:	https://doi.org/10.1007/978-981-10-1569-4
ISBN:	9789811015694

Functionalization of Carborane via Carboryne Intermediates
Zhao, Da.

Functionalization of Carborane via Carboryne Intermediates[electronic resource] /by Da Zhao. - 1st ed. 2016. - XVII, 170 p. 126 illus., 5 illus. in color.online resource. - Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053. - Springer Theses, Recognizing Outstanding Ph.D. Research,.

Introduction -- Regioselective Insertion of ο-Carborynes into α-C−H Bond of Tertiary Amines -- Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C–H Insertion Reaction -- Reaction of ο-Carboryne with Nitrones: A Formal [5 + 2] Cycloaddition -- 1,3-Dehydro-ο-Carborane: Generation and Reaction with Arenes -- Ene Reaction of 1,3-Dehydro-ο-Carborane -- Cage Boron Arylation of ο-Carborane via Metal-Free, Visible-Light-Mediated Radical Coupling -- Conclusion -- Experimental Section.

This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and more. However, the limited number of efficient synthetic methods for obtaining functional carborane materials has restricted their applications. The methodologies established in this thesis represent simple, yet powerful strategies to assemble previously inaccessible, useful complex molecules, which will also have a significant impact on future synthetic, cluster and materials chemistry. Moreover, it discusses the first method for the in situ generation of electrophilic boron radical using photocatalysis. .

ISBN: 9789811015694

Standard No.: 10.1007/978-981-10-1569-4doiSubjects--Topical Terms:

1148722
Organic chemistry.

LC Class. No.: QD415-436

Dewey Class. No.: 547

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