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Dynamical Decoupling in Distance Measurements by Double Electron-Electron Resonance

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Dynamical Decoupling in Distance Measurements by Double Electron-Electron Resonance/ by Janne Marie Soetbeer.
Author:	Soetbeer, Janne Marie.
Description:	XXI, 74 p. 24 illus.online resource. :
Contained By:	Springer Nature eBook
Subject:	Physical chemistry. -
Online resource:	https://doi.org/10.1007/978-3-658-14670-2
ISBN:	9783658146702

Dynamical Decoupling in Distance Measurements by Double Electron-Electron Resonance
Soetbeer, Janne Marie.

Dynamical Decoupling in Distance Measurements by Double Electron-Electron Resonance[electronic resource] /by Janne Marie Soetbeer. - 1st ed. 2016. - XXI, 74 p. 24 illus.online resource. - BestMasters,2625-3577. - BestMasters,.

The Spin Hamiltonian -- Pulsed EPR Experiments -- Relaxation Processes -- Dynamical Decoupling -- Model Systems.

Janne Marie Soetbeer determines the optimal dynamical decoupling (DD) scheme for efficient reduction of electron spin coherence loss in model systems for spin labelled biomolecules depending on their particular relaxation behavior. Extending the nth order DD scheme to double electron-electron resonance (DEER) experiments require the addition of multiple pump pulses for ≠ 1. Incomplete excitation of pump spin packets introduce signal artefacts which are minimized by pump pulse optimization including linear-chirp and asymmetric hyperbolic secant pulses. Prolonging the dipolar evolution time with decreased signal artefact allows to extent the measurable interspin distances in biomolecules which were otherwise not accessible due to spin echo relaxation. Contents The Spin Hamiltonian Pulsed EPR Experiments Relaxation Processes Dynamical Decoupling Model Systems Target Groups Lecturers and Students of Chemistry, especially of Physical Chemistry The Author Janne Marie Soetbeer completed her Master’s Thesis at the Swiss Federal Institute of Technology in Zurich, Switzerland. After a research stay with Prof. Dr. Robert Griffin at the Massachusetts Institute of Technology in Cambridge, USA, she will be returning to Zurich to start her PhD in Prof. Dr. Gunnar Jeschke’s group.

ISBN: 9783658146702

Standard No.: 10.1007/978-3-658-14670-2doiSubjects--Topical Terms:

1148725
Physical chemistry.

LC Class. No.: QD450-882

Dewey Class. No.: 541

Dynamical Decoupling in Distance Measurements by Double Electron-Electron Resonance
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