國立虎尾科技大學 |

Alkyne‐Based Nanostructures on Silver Substrates

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Alkyne‐Based Nanostructures on Silver Substrates / by Raphael Hellwig.
作者:	Hellwig, Raphael.
面頁冊數:	XV, 119 p. 44 illus., 43 illus. in color.online resource. :
Contained By:	Springer Nature eBook
標題:	Materials—Surfaces. -
電子資源:	https://doi.org/10.1007/978-3-030-00997-7
ISBN:	9783030009977

Alkyne‐Based Nanostructures on Silver Substrates
Hellwig, Raphael.

Alkyne‐Based Nanostructures on Silver Substrates [electronic resource] /by Raphael Hellwig. - 1st ed. 2018. - XV, 119 p. 44 illus., 43 illus. in color.online resource. - Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053. - Springer Theses, Recognizing Outstanding Ph.D. Research,.

Introduction -- Experimental Methods -- Silver-bis-acetylide Wires -- Fabrication of Graphdiyne Nanowires -- Metal Alkynyl 22/7 Complexes -- Ho-Catalyzed Cyclotrimerization -- Conclusion and Outlook.

Acetylenic precursors are important reactants for creating carbon-based architectures via linkage reactions. While their capability of forming intermolecular bonds is well investigated in solution, very few systematic studies have been carried out to create alkyne-based nanostructures on metal substrates under ultra-high vacuum conditions. Synthesizing extended and regular carbon scaffolds requires a detailed knowledge of alkyne chemistry in order to control reaction pathways and limit unwanted side reactions. Using the bottom-up approach on metal surfaces, the author establishes protocols to fabricate regular architectures built up by the on-surface formation of selective organometallic and C-C bonds with thoughtfully designed alkyne-functionalized monomers. The structural and functional properties of the resulting organometallic and covalent nanostructures are characterized by means of scanning tunneling microscopy. The results open up new perspectives in the fields of heterogeneous catalysis and the on-surface synthesis of functional interfaces under mild reaction conditions.

ISBN: 9783030009977

Standard No.: 10.1007/978-3-030-00997-7doiSubjects--Topical Terms:

1253588
Materials—Surfaces.

LC Class. No.: QC176.8.N35

Dewey Class. No.: 620.5

Alkyne‐Based Nanostructures on Silver Substrates
LDR:02707nam a22004095i 4500 001 989947
003 DE-He213
005 20200629130009.0
007 cr nn 008mamaa
008 201225s2018 gw | s |||| 0|eng d
020 $a 9783030009977 $9 978-3-030-00997-7
024 7 $a 10.1007/978-3-030-00997-7 $2 doi
035 $a 978-3-030-00997-7
050 4 $a QC176.8.N35
050 4 $a T174.7
072 7 $a TBN $2 bicssc
072 7 $a SCI050000 $2 bisacsh
072 7 $a TBN $2 thema
082 0 4 $a 620.5 $2 23
100 1 $a Hellwig, Raphael. $4 aut $4 http://id.loc.gov/vocabulary/relators/aut $3 1210682
245 1 0 $a Alkyne‐Based Nanostructures on Silver Substrates $h [electronic resource] / $c by Raphael Hellwig.
250 $a 1st ed. 2018.
264 1 $a Cham : $b Springer International Publishing : $b Imprint: Springer, $c 2018.
300 $a XV, 119 p. 44 illus., 43 illus. in color. $b online resource.
336 $a text $b txt $2 rdacontent
337 $a computer $b c $2 rdamedia
338 $a online resource $b cr $2 rdacarrier
347 $a text file $b PDF $2 rda
490 1 $a Springer Theses, Recognizing Outstanding Ph.D. Research, $x 2190-5053
505 0 $a Introduction -- Experimental Methods -- Silver-bis-acetylide Wires -- Fabrication of Graphdiyne Nanowires -- Metal Alkynyl 22/7 Complexes -- Ho-Catalyzed Cyclotrimerization -- Conclusion and Outlook.
520 $a Acetylenic precursors are important reactants for creating carbon-based architectures via linkage reactions. While their capability of forming intermolecular bonds is well investigated in solution, very few systematic studies have been carried out to create alkyne-based nanostructures on metal substrates under ultra-high vacuum conditions. Synthesizing extended and regular carbon scaffolds requires a detailed knowledge of alkyne chemistry in order to control reaction pathways and limit unwanted side reactions. Using the bottom-up approach on metal surfaces, the author establishes protocols to fabricate regular architectures built up by the on-surface formation of selective organometallic and C-C bonds with thoughtfully designed alkyne-functionalized monomers. The structural and functional properties of the resulting organometallic and covalent nanostructures are characterized by means of scanning tunneling microscopy. The results open up new perspectives in the fields of heterogeneous catalysis and the on-surface synthesis of functional interfaces under mild reaction conditions.
650 0 $a Materials—Surfaces. $3 1253588
650 0 $a Nanoscale science. $3 1253587
650 0 $a Nanoscience. $3 632473
650 0 $a Nanostructures. $3 561754
650 0 $a Organometallic chemistry . $3 1254952
650 0 $a Thin films. $3 560219
650 1 4 $a Nanoscale Science and Technology. $3 783795
650 2 4 $a Organometallic Chemistry. $3 674440
650 2 4 $a Surfaces and Interfaces, Thin Films. $3 671207
710 2 $a SpringerLink (Online service) $3 593884
773 0 $t Springer Nature eBook
776 0 8 $i Printed edition: $z 9783030009960
776 0 8 $i Printed edition: $z 9783030009984
830 0 $a Springer Theses, Recognizing Outstanding Ph.D. Research, $x 2190-5053 $3 1253569
856 4 0 $u https://doi.org/10.1007/978-3-030-00997-7
912 $a ZDB-2-PHA
912 $a ZDB-2-SXP
950 $a Physics and Astronomy (SpringerNature-11651)
950 $a Physics and Astronomy (R0) (SpringerNature-43715)