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Insights into the Chemistry of Organic Structure-Directing Agents in the Synthesis of Zeolitic Materials

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Insights into the Chemistry of Organic Structure-Directing Agents in the Synthesis of Zeolitic Materials/ edited by Luis Gómez-Hortigüela.
other author:	Gómez-Hortigüela, Luis.
Description:	VII, 250 p.online resource. :
Contained By:	Springer Nature eBook
Subject:	Physical chemistry. -
Online resource:	https://doi.org/10.1007/978-3-319-74289-2
ISBN:	9783319742892

Insights into the Chemistry of Organic Structure-Directing Agents in the Synthesis of Zeolitic Materials
Insights into the Chemistry of Organic Structure-Directing Agents in the Synthesis of Zeolitic Materials[electronic resource] /edited by Luis Gómez-Hortigüela. - 1st ed. 2018. - VII, 250 p.online resource. - Structure and Bonding,1750081-5993 ;. - Structure and Bonding,164.

Introduction of structure-directing phenomenon by organic molecules: general aspects -- Location of organic structure-directing agents by diffraction techniques -- Molecular modelling of organic structure-direction phenomena -- Beyond nitrogen organic structure-directing agents -- Role of supramolecular chemistry during templating phenomenon in zeolite synthesis -- Metal Complexes as structure directing agents for zeolites and related microporous materials -- Chiral organic structure-directing agents.

This edited volume focuses on the host-guest chemistry of organic molecules and inorganic systems during synthesis (structure-direction). Organic molecules have been used for many years in the synthesis of zeolitic nanoporous frameworks. The addition of these organic molecules to the zeolite synthesis mixtures provokes a particular ordering of the inorganic units around them that directs the crystallization pathway towards a particular framework type; hence they are called structure-directing agents. Their use has allowed the discovery of an extremely large number of new zeolite frameworks and compositions. This volume covers the main aspects of the use of organic molecules as structure-directing agents for the synthesis of zeolites, including first an introduction of the main concepts, then two chapters covering state-of-the-art techniques currently used to understand the structure-directing phenomenon (location of molecules by XRD and molecular modeling techniques). The most recent trends in the types of organic molecules used as structure-directing agents are also presented, including the use of metal-complexes, the use of non-ammonium-based molecules (mainly phosphorus-based compounds) and the role of supramolecular chemistry in designing new large organic structure-directing agents produced by self-aggregation. In addition the volume explores the latest research attempting to transfer the asymmetric nature of organic chiral molecules used as structure-directing agents to the zeolite lattice to produce chiral enantioselective frameworks, one of the biggest challenges today in materials chemistry. This volume has interdisciplinary appeal and will engage scholars from the zeolite community with a general interest in microporous materials, which involves not only zeolite scientists, but also researchers working on metal-organic framework materials. The concepts covered will also be of interest for researchers working on the application of materials after encapsulation of molecules of interest in post-synthetic treatments. Further the work explores the main aspects of host-guest chemistry in hybrid organo-inorganic templated materials, which covers all types of materials where organic molecules are used as templates and are confined within framework-structured inorganic materials (intercalation compounds). Therefore the volume is also relevant to the wider materials chemistry community.

ISBN: 9783319742892

Standard No.: 10.1007/978-3-319-74289-2doiSubjects--Topical Terms:

1148725
Physical chemistry.

LC Class. No.: QD450-882

Dewey Class. No.: 541

Insights into the Chemistry of Organic Structure-Directing Agents in the Synthesis of Zeolitic Materials
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