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Nanothermodynamics = theory and applications /

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Nanothermodynamics/ Dick Bedeaux, Signe Kjelstrup, Sondre K Schnell.
Reminder of title:	theory and applications /
Author:	Bedeaux, Dick,
other author:	Kjelstrup, Signe.
Published:	Singapore :World Scientific, : c2024.,
Description:	1 online resource (xiv, 400 p.)
Subject:	Thermodynamics. -
Online resource:	Access to full text is restricted to subscribers.
ISBN:	9789811275005

Nanothermodynamics = theory and applications /
Bedeaux, Dick,1941-

Nanothermodynamicstheory and applications /[electronic resource] :Dick Bedeaux, Signe Kjelstrup, Sondre K Schnell. - Singapore :World Scientific,c2024. - 1 online resource (xiv, 400 p.)

Includes bibliographical references and index.

Scope -- Large versus small thermodynamic systems -- Nanothermodynamics -- Statistical mechanics -- The small system method -- Ideal gas mixture with surface energy -- Internal energy -- Small system correlation functions -- Fluctuations -- Kirkwood-Buff integrals -- Pressures and partial molar enthalpies -- Hill's versus Gibbs' thermodynamics -- Maxwell-Stefan's and Fick's diffusivities -- Chemical reactions -- Adsorption on flat, large surfaces -- Adsorption on small, curved surfaces -- A representative elementary volume of a porous medium -- Integral and differential pressures in a slit-pore -- Entropy production in a porous medium -- Transport of a single fluid through a porous medium -- Stretching of small polymers -- Appendices.

"This book grew out of an idea to study properties of small subsystems of a large reservoir. Observations were at the time not explainable with standard thermodynamics. But the theory of Hill on thermodynamics of small systems provided the systematic procedure needed to address the problem. Following Hill, thermodynamics can be formulated for the nanoscale! The purpose of this book is to expand and demonstrate Hill's theory. The theory adds a new term to the fundamental Gibbs equation, that is specific for systems at the nanoscale. The properties that follow may be counter intuitive. The equation of state for a small system, for instance, is not given once and for all. We shall see that it changes with the environmental variables that control the small system. The statistical mechanical machinery remains as before, however. The world of small systems challenges the standard knowledge; that the number of particles in a system must be very large for thermodynamic equations to apply. We shall see that thermodynamic equations apply perfectly well also for small particle numbers, provided that small-system effects are accounted for correctly. In the world where size and shape are central, we shall find that equations of state can be used down to one particle in a box! There are scaling laws, which help us determine and understand the large system limit better! In the first part, the authors highlight the basic idea of the theory and provide a more systematic method, than used before. In the second part, the authors demonstrate the power of the theory in a set of central applications of nanoscience in and away from equilibrium, for other scientists to be inspired for further use"--

Mode of access: World Wide Web.

ISBN: 9789811275005

LCCN: 2023941927Subjects--Topical Terms:

596513
Thermodynamics.
Index Terms--Genre/Form:

554714
Electronic books.

LC Class. No.: TJ265

Dewey Class. No.: 621.4021

Nanothermodynamics = theory and applications /
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245 1 0 $a Nanothermodynamics $h [electronic resource] : $b theory and applications / $c Dick Bedeaux, Signe Kjelstrup, Sondre K Schnell.
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300 $a 1 online resource (xiv, 400 p.)
504 $a Includes bibliographical references and index.
505 0 $a Scope -- Large versus small thermodynamic systems -- Nanothermodynamics -- Statistical mechanics -- The small system method -- Ideal gas mixture with surface energy -- Internal energy -- Small system correlation functions -- Fluctuations -- Kirkwood-Buff integrals -- Pressures and partial molar enthalpies -- Hill's versus Gibbs' thermodynamics -- Maxwell-Stefan's and Fick's diffusivities -- Chemical reactions -- Adsorption on flat, large surfaces -- Adsorption on small, curved surfaces -- A representative elementary volume of a porous medium -- Integral and differential pressures in a slit-pore -- Entropy production in a porous medium -- Transport of a single fluid through a porous medium -- Stretching of small polymers -- Appendices.
520 $a "This book grew out of an idea to study properties of small subsystems of a large reservoir. Observations were at the time not explainable with standard thermodynamics. But the theory of Hill on thermodynamics of small systems provided the systematic procedure needed to address the problem. Following Hill, thermodynamics can be formulated for the nanoscale! The purpose of this book is to expand and demonstrate Hill's theory. The theory adds a new term to the fundamental Gibbs equation, that is specific for systems at the nanoscale. The properties that follow may be counter intuitive. The equation of state for a small system, for instance, is not given once and for all. We shall see that it changes with the environmental variables that control the small system. The statistical mechanical machinery remains as before, however. The world of small systems challenges the standard knowledge; that the number of particles in a system must be very large for thermodynamic equations to apply. We shall see that thermodynamic equations apply perfectly well also for small particle numbers, provided that small-system effects are accounted for correctly. In the world where size and shape are central, we shall find that equations of state can be used down to one particle in a box! There are scaling laws, which help us determine and understand the large system limit better! In the first part, the authors highlight the basic idea of the theory and provide a more systematic method, than used before. In the second part, the authors demonstrate the power of the theory in a set of central applications of nanoscience in and away from equilibrium, for other scientists to be inspired for further use"-- $c Publisher's website.
538 $a Mode of access: World Wide Web.
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650 0 $a Thermodynamics. $3 596513
650 0 $a Nanotechnology. $3 557660
655 0 $a Electronic books. $2 local $3 554714
700 1 $a Kjelstrup, Signe. $3 1458253
700 1 $a Schnell, Sondre K. $3 1458254
856 4 0 $u https://www.worldscientific.com/worldscibooks/10.1142/13372#t=toc $z Access to full text is restricted to subscribers.