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Design, synthesis, and properties of redox-active bisquinodimethanes

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Design, synthesis, and properties of redox-active bisquinodimethanes/ by Takashi Harimoto.
Author:	Harimoto, Takashi.
Published:	Singapore :Springer Nature Singapore : : 2025.,
Description:	xii, 148 p. :ill. (chiefly color), digital ; : 24 cm.;
Notes:	"Doctoral thesis accepted by Hokkaido University, Sapporo, Japan."
Contained By:	Springer Nature eBook
Subject:	Oxidation-reduction reaction. -
Online resource:	https://doi.org/10.1007/978-981-96-1591-9
ISBN:	9789819615919

Design, synthesis, and properties of redox-active bisquinodimethanes
Harimoto, Takashi.

Design, synthesis, and properties of redox-active bisquinodimethanes[electronic resource] /by Takashi Harimoto. - Singapore :Springer Nature Singapore :2025. - xii, 148 p. :ill. (chiefly color), digital ;24 cm. - Springer theses,2190-5061. - Springer theses..

"Doctoral thesis accepted by Hokkaido University, Sapporo, Japan."

1. General Introduction -- 2. Enhancement of NIR-Absorbing Ability of Bis(diarylmethylium)-Type Dicationic Dyes Based on an Ortho-Substitution Strategy -- 3. Octaarylated Bisquinodimethanes: Double Dynamic Redox Systems Enabling the Control of [n]Acene Structure and NIR Absorptions -- 4. Domino-Redox Reaction Induced by a Conformational Change Based on Dithiin Bisquinodimethane Skeleton.

This book focuses on the construction of redox systems composed of doubly fused para-quinodimethane (p-QD) units and on the elucidation of the unique redox behavior. p-QD is a class of non-aromatic π-conjugated compounds that is well-known to be interconvertible scaffolds in many response systems due to its contribution of resonance structure with a planar aromatic sextet ring. This book describes studies on a strategy for precisely controlling the frontier orbital levels of p-QD-based redox systems and a nature of cationic states of π-electron systems with doubly fused p-QD units. The author revealed that multi-redox unimolecular systems with cross-linking of the two sterically strained p-QD units exhibit unique hysteretic character or have a domino effect upon electron transfer, which cannot be achieved in a monomeric p-QD-based system. Thus, these studies are milestones in creating functional redox systems unprecedented dynamic redox (dyrex) behaviors. A study on cationic states of π-electron systems with doubly fused p-QD units and their intrinsic redox properties will lead to the development of unprecedented dyrex systems, the frontier orbital levels of which can be precisely controlled by input of external stimuli such as electric potential and heat. This book benefits chemists with a deeper understanding of the redox-active molecules.

ISBN: 9789819615919

Standard No.: 10.1007/978-981-96-1591-9doiSubjects--Topical Terms:

788263
Oxidation-reduction reaction.

LC Class. No.: QD716.O95

Dewey Class. No.: 541.393

Design, synthesis, and properties of redox-active bisquinodimethanes
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505 0 $a 1. General Introduction -- 2. Enhancement of NIR-Absorbing Ability of Bis(diarylmethylium)-Type Dicationic Dyes Based on an Ortho-Substitution Strategy -- 3. Octaarylated Bisquinodimethanes: Double Dynamic Redox Systems Enabling the Control of [n]Acene Structure and NIR Absorptions -- 4. Domino-Redox Reaction Induced by a Conformational Change Based on Dithiin Bisquinodimethane Skeleton.
520 $a This book focuses on the construction of redox systems composed of doubly fused para-quinodimethane (p-QD) units and on the elucidation of the unique redox behavior. p-QD is a class of non-aromatic π-conjugated compounds that is well-known to be interconvertible scaffolds in many response systems due to its contribution of resonance structure with a planar aromatic sextet ring. This book describes studies on a strategy for precisely controlling the frontier orbital levels of p-QD-based redox systems and a nature of cationic states of π-electron systems with doubly fused p-QD units. The author revealed that multi-redox unimolecular systems with cross-linking of the two sterically strained p-QD units exhibit unique hysteretic character or have a domino effect upon electron transfer, which cannot be achieved in a monomeric p-QD-based system. Thus, these studies are milestones in creating functional redox systems unprecedented dynamic redox (dyrex) behaviors. A study on cationic states of π-electron systems with doubly fused p-QD units and their intrinsic redox properties will lead to the development of unprecedented dyrex systems, the frontier orbital levels of which can be precisely controlled by input of external stimuli such as electric potential and heat. This book benefits chemists with a deeper understanding of the redox-active molecules.
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