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Construction and reactivity of Pt-based bi-component catalytic systems

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Construction and reactivity of Pt-based bi-component catalytic systems/ by Rentao Mu.
Author:	Mu, Rentao.
Published:	Berlin, Heidelberg :Springer Berlin Heidelberg : : 2017.,
Description:	xii, 90 p. :ill., digital ; : 24 cm.;
Contained By:	Springer eBooks
Subject:	Catalysis. -
Online resource:	http://dx.doi.org/10.1007/978-3-662-55244-5
ISBN:	9783662552445

Construction and reactivity of Pt-based bi-component catalytic systems
Mu, Rentao.

Construction and reactivity of Pt-based bi-component catalytic systems[electronic resource] /by Rentao Mu. - Berlin, Heidelberg :Springer Berlin Heidelberg :2017. - xii, 90 p. :ill., digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

Introduction -- Experimental Methods -- Construction and Reactivity of Pt-Ni Catalysts -- Modulating the Structure and Reactivity of Pt-Ni Catalysts -- Comparison of Pt-Fe and Pt-Ni Catalysts -- Reactivity of Graphene-confined Pt(111) Surfaces -- Conclusions.

In this thesis, the author outlines the construction of active structure and modulation of catalytic reactivity of Pt-based bi-component catalysts, from the model systems to real supported catalysts. The thesis investigates the promotion effect of the second components on catalytic performance of Pt catalysts, and presents the reversible generation of the "sandwich-like" structure of Pt-Ni catalysts, containing both surface NiO1-X and subsurface Ni by alternating redox treatments at medium temperature. With the aid of single layer graphene, the dynamic process of chemical reactions occurring on the Pt(111) surface can be visualized using in-situ LEEM and DUV-PEEM techniques, the results of which are included here. The author reveals that the graphene layer exhibits a strong confinement effect on the chemistry of molecules underneath and the intercalated CO can desorb from the Pt surface around room temperature and in UHV, which may promote the CO oxidation confined under graphene.

ISBN: 9783662552445

Standard No.: 10.1007/978-3-662-55244-5doiSubjects--Topical Terms:

673438
Catalysis.

LC Class. No.: QD505

Dewey Class. No.: 541.395

Construction and reactivity of Pt-based bi-component catalytic systems
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520 $a In this thesis, the author outlines the construction of active structure and modulation of catalytic reactivity of Pt-based bi-component catalysts, from the model systems to real supported catalysts. The thesis investigates the promotion effect of the second components on catalytic performance of Pt catalysts, and presents the reversible generation of the "sandwich-like" structure of Pt-Ni catalysts, containing both surface NiO1-X and subsurface Ni by alternating redox treatments at medium temperature. With the aid of single layer graphene, the dynamic process of chemical reactions occurring on the Pt(111) surface can be visualized using in-situ LEEM and DUV-PEEM techniques, the results of which are included here. The author reveals that the graphene layer exhibits a strong confinement effect on the chemistry of molecules underneath and the intercalated CO can desorb from the Pt surface around room temperature and in UHV, which may promote the CO oxidation confined under graphene.
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