國立虎尾科技大學 |

Advancing structure-property relationships in functional materials via thiol-ene photopolymerization.

Record Type:	Language materials, manuscript : Monograph/item
Title/Author:	Advancing structure-property relationships in functional materials via thiol-ene photopolymerization./
Author:	Donovan, Brian Richard.
Description:	1 online resource (175 pages)
Notes:	Source: Dissertation Abstracts International, Volume: 78-07(E), Section: B.
Subject:	Polymer chemistry. -
Online resource:	click for full text (PQDT)
ISBN:	9781369568882

Advancing structure-property relationships in functional materials via thiol-ene photopolymerization.
Donovan, Brian Richard.

Advancing structure-property relationships in functional materials via thiol-ene photopolymerization. - 1 online resource (175 pages)

Source: Dissertation Abstracts International, Volume: 78-07(E), Section: B.

Thesis (Ph.D.)--The University of Southern Mississippi, 2017.

Includes bibliographical references

Thiol-ene photopolymerizations provide a robust and versatile synthetic pathway to functional materials, and owing to the radical step-growth nature of polymerization and the resulting homogenous network structure, provide non-convoluted insight into how network chemistry influences and dictates macromolecular properties.

Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2018

Mode of access: World Wide Web

ISBN: 9781369568882Subjects--Topical Terms:

1182163
Polymer chemistry.
Index Terms--Genre/Form:

554714
Electronic books.

Advancing structure-property relationships in functional materials via thiol-ene photopolymerization.
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100 1 $a Donovan, Brian Richard. $3 1187172
245 1 0 $a Advancing structure-property relationships in functional materials via thiol-ene photopolymerization.
264 0 $c 2017
300 $a 1 online resource (175 pages)
336 $a text $b txt $2 rdacontent
337 $a computer $b c $2 rdamedia
338 $a online resource $b cr $2 rdacarrier
500 $a Source: Dissertation Abstracts International, Volume: 78-07(E), Section: B.
500 $a Adviser: Derek L. Patton.
502 $a Thesis (Ph.D.)--The University of Southern Mississippi, 2017.
504 $a Includes bibliographical references
520 $a Thiol-ene photopolymerizations provide a robust and versatile synthetic pathway to functional materials, and owing to the radical step-growth nature of polymerization and the resulting homogenous network structure, provide non-convoluted insight into how network chemistry influences and dictates macromolecular properties.
520 $a The first facet of this dissertation focuses on the design and synthesis of bio-inspired, thin film adhesives for dry and aqueous adhesion. Drawing inspiration from the intertidal marine mussel, Chapter II details the synthesis of adhesive networks containing a monofunctional catechol-based monomer. The inclusion of a catechol group resulted in significant improvements in adhesion on a variety of substrates. In Chapter III, the inclusion of simple hydrophobic groups in the adhesive thiol-ene networks to improve underwater adhesion is reported. The presence of hydrophobic groups effectively push water away from the adhesive resin/substrate interface, facilitating adhesive interaction underwater. Further, the influence of the catechol (a known radical scavenger) and the hydrophobic groups (commonly considered non-adhesive) on polymerization kinetics, thermal mechanical, and mechanical properties was determined.
520 $a The second facet of this dissertation focuses on the synthesis of semi-fluorinated polymer networks, as outlined in Chapter IV. Fluorine groups impart several advantageous properties to polymeric materials including increased mechanical strength, chemical and thermal stability, and unique optical and wetting properties. As such, the inclusion of the trifluorovinyl ether group in a thiol-ene photopolymerization resulted in the rapid and efficient synthesis of semi-fluorinated networks, exhibiting significant increases in thermomechanical and mechanical properties as a function of fluorine content.
533 $a Electronic reproduction. $b Ann Arbor, Mich. : $c ProQuest, $d 2018
538 $a Mode of access: World Wide Web
650 4 $a Polymer chemistry. $3 1182163
650 4 $a Materials science. $3 557839
650 4 $a Chemistry. $3 593913
655 7 $a Electronic books. $2 local $3 554714
690 $a 0495
690 $a 0794
690 $a 0485
710 2 $a ProQuest Information and Learning Co. $3 1178819
710 2 $a The University of Southern Mississippi. $b Polymers and High Performance Materials. $3 1187173
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10256891 $z click for full text (PQDT)