國立虎尾科技大學 |

Molecular symmetry, super-rotation, and semiclassical motion = new ideas for solving old problems /

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Molecular symmetry, super-rotation, and semiclassical motion/ by Hanno Schmiedt.
Reminder of title:	new ideas for solving old problems /
Author:	Schmiedt, Hanno.
Published:	Cham :Springer International Publishing : : 2017.,
Description:	ix, 171 p. :ill., digital ; : 24 cm.;
Contained By:	Springer eBooks
Subject:	Symmetry (Physics) -
Online resource:	http://dx.doi.org/10.1007/978-3-319-66071-4
ISBN:	9783319660714

Molecular symmetry, super-rotation, and semiclassical motion = new ideas for solving old problems /
Schmiedt, Hanno.

Molecular symmetry, super-rotation, and semiclassical motionnew ideas for solving old problems /[electronic resource] :by Hanno Schmiedt. - Cham :Springer International Publishing :2017. - ix, 171 p. :ill., digital ;24 cm. - Springer series on atomic, optical, and plasma physics,v.971615-5653 ;. - Springer series on atomic, optical, and plasma physics ;71..

New Ideas for Solving Old Problems - An Introduction -- Basic Concepts -- Schur-Weyl Duality in Molecules -- Reactive Collisions -- Introducing Extreme Floppiness -- Symmetry Beyond Perturbation Theory -- The Molecular Super-rotor.

This book presents a range of fundamentally new approaches to solving problems involving traditional molecular models. Fundamental molecular symmetry is shown to open new avenues for describing molecular dynamics beyond standard perturbation techniques. Traditional concepts used to describe molecular dynamics are based on a few fundamental assumptions, the ball-and-stick picture of molecular structure and the respective perturbative treatment of different kinds of couplings between otherwise separate motions. The book points out the conceptual limits of these models and, by focusing on the most essential idea of theoretical physics, namely symmetry, shows how to overcome those limits by introducing fundamentally new concepts. The book begins with an introduction to molecular symmetry in general, followed by a discussion of nuclear spin symmetry. Here, a new correlation between identical particle exchange and spin angular momentum symmetry of nuclei is exhibited. The central part of the book is the discussion of extremely floppy molecules, which are not describable in the framework of traditional theories. The book introduces a fundamentally new approach to describing the molecular dynamics of these molecules - the super-rotor model, which is based on a five-dimensional symmetry that has never been observed in molecules before. By applying the super-rotor theory to the prototype of floppy molecules, protonated methane, this model can consistently predict the symmetry and energy of low-energy states, which were characterized experimentally only a few years ago. The theoretical predictions agree with the experimental results, which makes the prospect of further developing the super-rotor theory and applying it to other molecules a promising one. In the final section, the book also covers the topic of ultrafast rotations, where usual quantum calculations reach their natural limits. A semi-classical method for determining rotational energies, developed in the early 1990s, is shown to be attachable to quantum calculations of the vibrational states. This new combined method is suitable for efficiently calculating ro-vibrational energies, even for molecular states with large angular momentum.

ISBN: 9783319660714

Standard No.: 10.1007/978-3-319-66071-4doiSubjects--Topical Terms:

591962
Symmetry (Physics)

LC Class. No.: QC174.17.S9 / S36 2017

Dewey Class. No.: 539.725

Molecular symmetry, super-rotation, and semiclassical motion = new ideas for solving old problems /
LDR:03536nam a2200325 a 4500 001 924418
003 DE-He213
005 20180327141834.0
006 m d
007 cr nn 008maaau
008 190625s2017 gw s 0 eng d
020 $a 9783319660714 $q (electronic bk.)
020 $a 9783319660707 $q (paper)
024 7 $a 10.1007/978-3-319-66071-4 $2 doi
035 $a 978-3-319-66071-4
040 $a GP $c GP
041 0 $a eng
050 4 $a QC174.17.S9 $b S36 2017
072 7 $a PHN $2 bicssc
072 7 $a SCI074000 $2 bisacsh
082 0 4 $a 539.725 $2 23
090 $a QC174.17.S9 $b S354 2017
100 1 $a Schmiedt, Hanno. $3 1201395
245 1 0 $a Molecular symmetry, super-rotation, and semiclassical motion $h [electronic resource] : $b new ideas for solving old problems / $c by Hanno Schmiedt.
260 $a Cham : $c 2017. $b Springer International Publishing : $b Imprint: Springer,
300 $a ix, 171 p. : $b ill., digital ; $c 24 cm.
490 1 $a Springer series on atomic, optical, and plasma physics, $x 1615-5653 ; $v v.97
505 0 $a New Ideas for Solving Old Problems - An Introduction -- Basic Concepts -- Schur-Weyl Duality in Molecules -- Reactive Collisions -- Introducing Extreme Floppiness -- Symmetry Beyond Perturbation Theory -- The Molecular Super-rotor.
520 $a This book presents a range of fundamentally new approaches to solving problems involving traditional molecular models. Fundamental molecular symmetry is shown to open new avenues for describing molecular dynamics beyond standard perturbation techniques. Traditional concepts used to describe molecular dynamics are based on a few fundamental assumptions, the ball-and-stick picture of molecular structure and the respective perturbative treatment of different kinds of couplings between otherwise separate motions. The book points out the conceptual limits of these models and, by focusing on the most essential idea of theoretical physics, namely symmetry, shows how to overcome those limits by introducing fundamentally new concepts. The book begins with an introduction to molecular symmetry in general, followed by a discussion of nuclear spin symmetry. Here, a new correlation between identical particle exchange and spin angular momentum symmetry of nuclei is exhibited. The central part of the book is the discussion of extremely floppy molecules, which are not describable in the framework of traditional theories. The book introduces a fundamentally new approach to describing the molecular dynamics of these molecules - the super-rotor model, which is based on a five-dimensional symmetry that has never been observed in molecules before. By applying the super-rotor theory to the prototype of floppy molecules, protonated methane, this model can consistently predict the symmetry and energy of low-energy states, which were characterized experimentally only a few years ago. The theoretical predictions agree with the experimental results, which makes the prospect of further developing the super-rotor theory and applying it to other molecules a promising one. In the final section, the book also covers the topic of ultrafast rotations, where usual quantum calculations reach their natural limits. A semi-classical method for determining rotational energies, developed in the early 1990s, is shown to be attachable to quantum calculations of the vibrational states. This new combined method is suitable for efficiently calculating ro-vibrational energies, even for molecular states with large angular momentum.
650 0 $a Symmetry (Physics) $3 591962
650 0 $a Molecular theory. $3 636402
650 1 4 $a Physics. $3 564049
650 2 4 $a Atomic/Molecular Structure and Spectra. $3 783942
650 2 4 $a Numerical and Computational Physics, Simulation. $3 1112293
650 2 4 $a Physical Chemistry. $3 668972
650 2 4 $a Vibration, Dynamical Systems, Control. $3 670825
710 2 $a SpringerLink (Online service) $3 593884
773 0 $t Springer eBooks
830 0 $a Springer series on atomic, optical, and plasma physics ; $v 71. $3 885076
856 4 0 $u http://dx.doi.org/10.1007/978-3-319-66071-4
950 $a Physics and Astronomy (Springer-11651)